Article,

Synthesis and Crystal Structure of a Five-Coordinate Complex of Copper(II) with 4-Nitrobenzenesulfonate and 2, 2 `-Bipyridine

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ACTA CHIMICA SLOVENICA, 59 (2): 289-293 (2012)

Abstract

Cu(bipy)(2)Cl(nbs) (1) (bipy = 2,2'-bipyridine, nbs = 4-nitrobenzenesulfonate) was obtained from the reaction of 4-nitrobenzenesulfonyl chloride and 2-amine-4-methylopyridine with CuCl2 in the presence of 2,2'-bipyridine and characterized by elemental analysis, IR spectra and X-ray single-crystal diffraction. The asymmetric unit of (1) contains the cationic complex Cu(bipy)(2)Cl(+) and, in the outer coordination sphere, an (nbs)(-) counter ion.

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