Article,

Thermodynamics of electrolytes. 12. Dielectric properties of water and Debye-Hueckel parameters to 350 °C and 1 kbar

, and .
The Journal of Physical Chemistry, 83 (12): 1599-1603 (1979)
DOI: 10.1021/j100475a009

Abstract

In preparation for work with aqueous electrolytes at above saturation pressures and at temperatures to 350°C, an equation was developed for the representation of the dielectric constant of water over this range. With this equation and an equation of state for water, the Debye-Huckel limiting law parameters for osmotic and activity coefficients, enthalpies, heat capacities, volumes, compressibilities, and expansibilities were calculated and are presented.

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