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Enantioselective Nitrogen Transfer to Sulfides from Nitridomanganese(V) Complexes
Helvetica Chimica Acta, 85 (11): 3773--3784 (2002)
DOI: 10.1002/1522-2675(200211)85:11<3773::AID-HLCA3773>3.0.CO;2-O
Аннотация
We describe the facile preparation of novel, optically active nitridomanganese(V) complexes which serve as reagents for the electrophilic amination of sulfides. This amination method has several appealing features, including: i) the facile preparation of large quantities of the starting nitridomanganese reagent 3, ii) the preparation of acylsulfilimines 2 in optically active form, and iii) the mild reaction conditions employed.
