%0 Journal Article %1 GANSKE:1991p3310 %A GANSKE, JA %A EZELL, MJ %A BERKO, HN %A FinlaysonPitts, BJ %D 1991 %J Chemical Physics Letters %K Antarctic Chloride, Cino, Cl, Depletion H2O, Hcl, Ice N2O5, Nitrosyl Ozone Surfaces, %N 1-2 %P 204--210 %T THE REACTION OF OH WITH C1NO2 AT 298-K - KINETICS AND MECHANISMS %U http://www.google.com/search?client=safari&rls=en-us&q=THE+REACTION+OF+OH+WITH+C1NO2+AT+298-K+-+KINETICS+AND+MECHANISMS&ie=UTF-8&oe=UTF-8 %V 179 %X The kinetics of the gas phase reaction between OH and CINO2 have been studied in a fast flow discharge system (FFDS) at 298 K. The rate constant for the reaction was determined in phosphoric acid or halocarbon wax coated flow tubes to be (3.5 +/- 0.7) x 10(-14) cm3 molecule-1 s-1, where the uncertainty takes into account possible systematic errors and is greater than 2-sigma. HOCl was shown by mass spectrometry to be the major product. Using for comparison the OH + ClNO reaction, these data show that channel (la) OH + ClNO2 --> HOCl + NO2 must account for greater-than-or-equal-to 90% of the OH + ClNO2 reaction. A second possible channel (1b) OH + ClNO2 --> HNO3 + Cl is not significant. The atmospheric implications of these results are discussed.

@article{GANSKE:1991p3310, abstract = {The kinetics of the gas phase reaction between OH and CINO2 have been studied in a fast flow discharge system (FFDS) at 298 K. The rate constant for the reaction was determined in phosphoric acid or halocarbon wax coated flow tubes to be (3.5 +/- 0.7) x 10(-14) cm3 molecule-1 s-1, where the uncertainty takes into account possible systematic errors and is greater than 2-sigma. HOCl was shown by mass spectrometry to be the major product. Using for comparison the OH + ClNO reaction, these data show that channel (la) OH + ClNO2 --> HOCl + NO2 must account for greater-than-or-equal-to 90% of the OH + ClNO2 reaction. A second possible channel (1b) OH + ClNO2 --> HNO3 + Cl is not significant. The atmospheric implications of these results are discussed.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {CALIF STATE UNIV FULLERTON,DEPT CHEM {\&} BIOCHEM,FULLERTON,CA 92634}, author = {GANSKE, JA and EZELL, MJ and BERKO, HN and FinlaysonPitts, BJ}, biburl = {https://www.bibsonomy.org/bibtex/218ecfd3201a31924a0ddb656df0fc713/gsmith}, date-added = {2010-04-29 13:10:12 -0400}, date-modified = {2010-04-29 13:10:26 -0400}, interhash = {846796054a12fd4bf22bddf4a61fdaf6}, intrahash = {18ecfd3201a31924a0ddb656df0fc713}, journal = {Chemical Physics Letters}, keywords = {Antarctic Chloride, Cino, Cl, Depletion H2O, Hcl, Ice N2O5, Nitrosyl Ozone Surfaces,}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Chemical%20Physics%20Letters/1991/Chemical%20Physics%20Letters,%20179,%20204-210%201991.pdf}, month = Jan, number = {1-2}, pages = {204--210}, pmid = {A1991FH14300036}, rating = {0}, timestamp = {2010-06-22T19:39:21.000+0200}, title = {THE REACTION OF OH WITH C1NO2 AT 298-K - KINETICS AND MECHANISMS}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3310}, url = {http://www.google.com/search?client=safari&rls=en-us&q=THE+REACTION+OF+OH+WITH+C1NO2+AT+298-K+-+KINETICS+AND+MECHANISMS&ie=UTF-8&oe=UTF-8}, volume = 179, year = 1991 }