%0 Journal Article %1 Crounse:2006p1152 %A Crounse, J %A McKinney, K %A Kwan, A %A Wennberg, P %D 2006 %J Analytical Chemistry %K imported %N 19 %P 6726--6732 %T Measurement of gas-phase hydroperoxides by chemical ionization mass spectrometry %U http://links.isiglobalnet2.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=mekentosj&SrcApp=Papers&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000240861700013 %V 78 %X A new method for the detection of gas-phase hydroperoxides is described. The clustering chemistry of CF3O- is exploited to produce speciated measurements of several hydroperoxides with high sensitivity and fast time response. Correspondence of airborne observations made with this technique and the established HPLC method is illustrated. CF3O- appears to be a highly versatile reagent ion for measurements of both weak and strong acids in the atmosphere.

@article{Crounse:2006p1152, abstract = {A new method for the detection of gas-phase hydroperoxides is described. The clustering chemistry of CF3O- is exploited to produce speciated measurements of several hydroperoxides with high sensitivity and fast time response. Correspondence of airborne observations made with this technique and the established HPLC method is illustrated. CF3O- appears to be a highly versatile reagent ion for measurements of both weak and strong acids in the atmosphere.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Crounse, JD CALTECH, Div Chem {\&} Chem Engn, MC 150-21,1200 E Calif Blvd, Pasadena, CA 91125 USA CALTECH, Div Chem {\&} Chem Engn, Pasadena, CA 91125 USA CALTECH, Div Geol {\&} Planetary Sci, Pasadena, CA 91125 USA CALTECH, Div Engn {\&} Appl Sci, Pasadena, CA 91125 USA}, author = {Crounse, J and McKinney, K and Kwan, A and Wennberg, P}, biburl = {https://www.bibsonomy.org/bibtex/28ceb3d86eb20403876eda033876eccec/gsmith}, date-added = {2010-03-10 16:47:15 -0500}, date-modified = {2010-03-10 16:48:23 -0500}, interhash = {86c73895b3daf630e6d729e762ab6b41}, intrahash = {8ceb3d86eb20403876eda033876eccec}, journal = {Analytical Chemistry}, keywords = {imported}, label = {rec-number 1292}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Analytical%20Chemistry/2006/Analytical%20Chemistry,%2078,%206726-6732%202006.pdf}, month = Oct, note = {089DY Times Cited:0 Cited References Count:35}, number = 19, pages = {6726--6732}, pmid = {000240861700013}, rating = {0}, timestamp = {2010-06-22T19:38:58.000+0200}, title = {Measurement of gas-phase hydroperoxides by chemical ionization mass spectrometry}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p1152}, url = {http://links.isiglobalnet2.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=mekentosj&SrcApp=Papers&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000240861700013}, volume = 78, year = 2006 }