%0 Journal Article %1 Kurth2000c %A Kurth, DG %A Volkmer, D %A Ruttorf, M %A Richter, B %A Muller, A %C 1155 16TH ST, NW, WASHINGTON, DC 20036 USA %D 2000 %I AMER CHEMICAL SOC %J CHEMISTRY OF MATERIALS %K dgkurth %N 10 %P 2829+ %T Ultrathin composite films incorporating the nanoporous isopolyoxomolybdate ``Keplerate'' (NH4)(42)Mo132O372(CH3COO)(30)(H2O)(72) %V 12 %X Ultrathin Composite Films Incorporating the Nanoporous Isopolyoxomolybdate ``Keplerate'' (NH4)(42)Mo132O372- (CH3COO)(30)(H2O)(72) The giant, nanoporous Keplerate (NH4)(42)- Mo132O372(CH3COO)(30)(H2O)(72) was incorporated into a permeable ultrathin film using a stepwise self-assembly strategy. Alternating adsorption of the Keplerate anions and PAH results in single layers with an apparent surface coverage of approximate to 50\%. Such permeable composite coatings may lead into a practical approach to utilize nanoporous polyoxometalate clusters in sensors or heterogeneous catalysts.

@article{Kurth2000c, abstract = {Ultrathin Composite Films Incorporating the Nanoporous Isopolyoxomolybdate ``Keplerate{''} (NH4)(42){[}Mo132O372- (CH3COO)(30)(H2O)(72)] The giant, nanoporous Keplerate (NH4)(42)- {[}Mo132O372(CH3COO)(30)(H2O)(72)] was incorporated into a permeable ultrathin film using a stepwise self-assembly strategy. Alternating adsorption of the Keplerate anions and PAH results in single layers with an apparent surface coverage of approximate to 50\%. Such permeable composite coatings may lead into a practical approach to utilize nanoporous polyoxometalate clusters in sensors or heterogeneous catalysts.}, added-at = {2011-01-12T11:47:23.000+0100}, address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA}, affiliation = {Kurth, DG (Reprint Author), Max Planck Inst Colloids \& Interfaces, D-14424 Potsdam, Germany. Max Planck Inst Colloids \& Interfaces, D-14424 Potsdam, Germany. Univ Bielefeld, Dept Inorgan Chem 1, D-33501 Bielefeld, Germany.}, author = {Kurth, DG and Volkmer, D and Ruttorf, M and Richter, B and Muller, A}, biburl = {https://www.bibsonomy.org/bibtex/2a0d909a4254186b37b866dc37b99dc6c/lctm}, doc-delivery-number = {366YT}, interhash = {c30d43297afe1020d90d5d33b6b2d32c}, intrahash = {a0d909a4254186b37b866dc37b99dc6c}, issn = {0897-4756}, journal = {CHEMISTRY OF MATERIALS}, journal-iso = {Chem. Mat.}, keywords = {dgkurth}, keywords-plus = {MULTILAYER FILMS; MOLYBDENUM OXIDE; POLYELECTROLYTE}, language = {English}, month = OCT, number = 10, number-of-cited-references = {14}, pages = {2829+}, publisher = {AMER CHEMICAL SOC}, subject-category = {Chemistry, Physical; Materials Science, Multidisciplinary}, times-cited = {95}, timestamp = {2011-01-12T11:47:23.000+0100}, title = {Ultrathin composite films incorporating the nanoporous isopolyoxomolybdate ``Keplerate{''} (NH4)(42){[}Mo132O372(CH3COO)(30)(H2O)(72)]}, type = {Article}, unique-id = {ISI:000090034400004}, volume = 12, year = 2000 }