%0 Journal Article %1 ISI:000251977500039 %A Rayati, Saeed %A Sadeghzadeh, Nasrin %A Khavasi, Hamid Reza %C PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS %D 2007 %I ELSEVIER SCIENCE BV %J INORGANIC CHEMISTRY COMMUNICATIONS %K Schiff base; complex; crystal oxidation; structure} {vanadium %N 12 %P 1545-1548 %R 10.1016/j.inoche.2007.09.023 %T A new di-mu-oxo bisoxovanadium(V) complex containing Schiff base ligand derived from 1,2-diaminopropane and 2 `-hydroxy-4 `-methoxyacetophenone: Synthesis, structure and catalytic properties %V 10 %X New dioxovanadium(V) complex bearing tridentate ligand of 1:1 condensation of 1,2-propylenediamine and 2'-hydroxy-4'-methoxyacetophenone has been synthesized and characterized by IR and H-1 NMR spectroscopy and elemental analysis. The single-crystal structure of the complex shows that each vanadium(V) ion is six-coordinate through three bonds to oxo groups and through bonds to the tridentate Schiff base ligand. The title complex is used as catalyst for the selective epoxidation of cyclooctene. The catalytic system described here is an efficient and inexpensive method for the oxidation of olefins, with the advantages of high activity, selectivity, and short reaction time. (C) 2007 Elsevier B.V. All rights reserved.

@article{ISI:000251977500039, abstract = {{New dioxovanadium(V) complex bearing tridentate ligand of 1:1 condensation of 1,2-propylenediamine and 2'-hydroxy-4'-methoxyacetophenone has been synthesized and characterized by IR and H-1 NMR spectroscopy and elemental analysis. The single-crystal structure of the complex shows that each vanadium(V) ion is six-coordinate through three bonds to oxo groups and through bonds to the tridentate Schiff base ligand. The title complex is used as catalyst for the selective epoxidation of cyclooctene. The catalytic system described here is an efficient and inexpensive method for the oxidation of olefins, with the advantages of high activity, selectivity, and short reaction time. (C) 2007 Elsevier B.V. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS}}, affiliation = {{Rayati, S (Reprint Author), Zanjan Univ, Fac Sci, Dept Chem, POB 45195-313, Zanjan, Iran. Rayati, Saeed; Sadeghzadeh, Nasrin, Zanjan Univ, Fac Sci, Dept Chem, Zanjan, Iran. Khavasi, Hamid Reza, Shaheed Beheshti Univ Med Sci, Dept Chem, Tehran 1983963113, Iran.}}, author = {Rayati, Saeed and Sadeghzadeh, Nasrin and Khavasi, Hamid Reza}, author-email = {{srayati@mail.znu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2ce665238e3e7e998983ac37b6c027eda/hkhavasi}, cited-references = {{Allen FH, 2002, ACTA CRYSTALLOGR B, V58, P380, DOI 10.1107/S0108768102003890. Butler A, 1998, CURR OPIN CHEM BIOL, V2, P279, DOI 10.1016/S1367-5931(98)80070-7. BUTLER A, 1994, CHEM REV, V94, P625, DOI 10.1021/cr00027a004. Canali L, 1999, CHEM SOC REV, V28, P85, DOI 10.1039/a806483k. CARNS DC, 1996, SULFUR SILICON, V109, P245. CRAIG JA, 1989, INORG CHEM, V28, P2082, DOI 10.1021/ic00310a015. Crans DC, 2000, J INORG BIOCHEM, V80, P123, DOI 10.1016/S0162-0134(00)00048-9. Crans DC, 2004, CHEM REV, V104, P849, DOI 10.1021/cr020607t. Crans DC, 2003, COORDIN CHEM REV, V237, P13, DOI 10.1016/S0010-8545(02)00292-8. Crans DC, 2000, INORG CHEM, V39, P4409, DOI 10.1021/ic9908367. Fites RJ, 2006, INORG CHIM ACTA, V359, P248, DOI 10.1016/j.ica.2005.07.024. Goldwaser I, 2000, J INORG BIOCHEM, V80, P21, DOI 10.1016/S0162-0134(00)00035-0. Harrowfield JM, 1996, AUST J CHEM, V49, P1165, DOI 10.1071/CH9961165. Hoshina G, 1998, INORG CHEM, V37, P142, DOI 10.1021/ic9705958. Jacobsen E. N., 1995, COMPREHENSIVE ORGANO, V12, P1097. KATSUKI T, 1995, COORDIN CHEM REV, V140, P189, DOI 10.1016/0010-8545(94)01124-T. Kwiatkowski E, 2006, POLYHEDRON, V25, P2809, DOI 10.1016/j.poly.2006.04.004. Majlesi K, 2006, J MOL LIQ, V125, P62, DOI 10.1016/j.molliq.2005.11.017. Maurya MR, 2006, INORG CHIM ACTA, V359, P2439, DOI 10.1016/j.ica.2006.02.032. Maurya MR, 2006, J MOL CATAL A-CHEM, V250, P190, DOI 10.1016/j.molcata.2006.01.058. Maurya MR, 2004, CATAL COMMUN, V5, P563, DOI 10.1016/j.catcom.2004.07.004. Maurya RC, 2007, J MOL STRUCT, V833, P133, DOI 10.1016/j.molstruc.2006.09.022. MUKHERJEE S, 2006, APPL CATAL A-GEN, V31, P79. Mukherjee S, 2006, APPL CATAL B-ENVIRON, V68, P12, DOI 10.1016/j.apcatb.2006.07.015. Pohlmann A, 2005, INORG CHEM COMMUN, V8, P289, DOI 10.1016/j.inoche.2004.12.028. Sakurai H, 2002, COORDIN CHEM REV, V226, P187, DOI 10.1016/S0010-8545(01)00447-7. Salavati-Niasari M, 2004, J MOL CATAL A-CHEM, V221, P169, DOI 10.1016/j.molcata.2004.07.007. Thompson KH, 1999, CHEM REV, V99, P2561, DOI 10.1021/cr980427c. Thompson KH, 2001, COORDIN CHEM REV, V219, P1033, DOI 10.1016/S0010-8545(01)00395-2. TOPICH J, 1984, INORG CHEM, V23, P3202, DOI 10.1021/ic00188a034. Wever R., 2001, HDB METALLOPROTEINS, V2, P1417.}}, doc-delivery-number = {{245ZO}}, doi = {{10.1016/j.inoche.2007.09.023}}, interhash = {d6f68f9335ed0fda466a4961bac8bae8}, intrahash = {ce665238e3e7e998983ac37b6c027eda}, issn = {{1387-7003}}, journal = {{INORGANIC CHEMISTRY COMMUNICATIONS}}, journal-iso = {{Inorg. Chem. Commun.}}, keywords = {Schiff base; complex; crystal oxidation; structure} {vanadium}, keywords-plus = {{OXYGEN ATOM TRANSFER; DIOXOVANADIUM(V) COMPLEXES; VANADIUM HALOPEROXIDASES; CHEMISTRY; CYCLOHEXENE; OXIDATION; ACTIVATION; COMPOUND}}, language = {{English}}, month = {{DEC}}, number = {{12}}, number-of-cited-references = {{31}}, pages = {{1545-1548}}, publisher = {{ELSEVIER SCIENCE BV}}, research-areas = {{Chemistry}}, times-cited = {{32}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{A new di-mu-oxo bis{[}oxovanadium(V)] complex containing Schiff base ligand derived from 1,2-diaminopropane and 2 `-hydroxy-4 `-methoxyacetophenone: Synthesis, structure and catalytic properties}}, type = {{Article}}, unique-id = {{ISI:000251977500039}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{4}}, volume = {{10}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2007}} }