%0 Journal Article %1 citeulike:2439865 %A Tsonopoulos, C. %A Newman, John %A Prausnitz, J. M. %D 1971 %J Chemical Engineering Science %K 82c24-time-dependent-statistical-mechanics-of-interface-problems %N 6 %P 817--827 %R 10.1016/0009-2509(71)83043-9 %T Rapid aging and dynamic surface tension of dilute aqueous solutions %U http://dx.doi.org/10.1016/0009-2509(71)83043-9 %V 26 %X The mechanism controlling rapid aging of surfaces of aqueous solutions is considered with reference to the variation of dynamic surface tension with time. The Ward--Tordai and Sutherland results for the diffusion-controlled mechanism are critically discussed and a new surface model is introduced which reduces to the Sutherland result as a special case. The diffusion-controlled mechanism is inadequate for aqueous solutions of mono-alcohols. Satifactory agreement between experiment and theory is obtained through introduction of first-order adsorption kinetics, but only for values of the adsorption rate constant which make the governing relation a complex-variable equation.

@article{citeulike:2439865, abstract = {{The mechanism controlling rapid aging of surfaces of aqueous solutions is considered with reference to the variation of dynamic surface tension with time. The Ward--Tordai and Sutherland results for the diffusion-controlled mechanism are critically discussed and a new surface model is introduced which reduces to the Sutherland result as a special case. The diffusion-controlled mechanism is inadequate for aqueous solutions of mono-alcohols. Satifactory agreement between experiment and theory is obtained through introduction of first-order adsorption kinetics, but only for values of the adsorption rate constant which make the governing relation a complex-variable equation.}}, added-at = {2017-06-29T07:13:07.000+0200}, author = {Tsonopoulos, C. and Newman, John and Prausnitz, J. M.}, biburl = {https://www.bibsonomy.org/bibtex/2de505b71f00d2b565a42435a52be2c40/gdmcbain}, citeulike-article-id = {2439865}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/0009-2509(71)83043-9}, citeulike-linkout-1 = {http://www.sciencedirect.com/science/article/B6TFK-444GS32-PP/2/f4dc728f28fc352f9a9dc8b39b228110}, doi = {10.1016/0009-2509(71)83043-9}, interhash = {e14fd5b2b50a5c3352105e7abdcd9a4e}, intrahash = {de505b71f00d2b565a42435a52be2c40}, journal = {Chemical Engineering Science}, keywords = {82c24-time-dependent-statistical-mechanics-of-interface-problems}, month = jun, number = 6, pages = {817--827}, posted-at = {2008-02-28 05:04:54}, priority = {2}, timestamp = {2017-06-29T07:13:07.000+0200}, title = {{Rapid aging and dynamic surface tension of dilute aqueous solutions}}, url = {http://dx.doi.org/10.1016/0009-2509(71)83043-9}, volume = 26, year = 1971 }