%0 Journal Article %1 berghold97a %A Berghold, G. %A van der Schoot, P. %A Seidel, C. %D 1997 %J J. Chem. Phys. %K MC, PE charge distribution, for rigid rod theorie variational %N 19 %P 8083 %T Equilibrium charge distribution on weak polyelectrolytes %V 107 %X Density functional theory and Monte Carlo simulations have been used to study the non-uniform equilibrium charge distribution on weak polyelectrolytes. For rigid rods, linearized density functional theory and simulation data show good agreement in a fairly wide parameter range. In the central part of the rod there appears a slight depletion of charge which is accumulated at the ends within a range of the order of the Debye length. For flexible chains, the simulations show an enhancement of the non-uniformity of the charge distribution.

@article{berghold97a, abstract = {Density functional theory and Monte Carlo simulations have been used to study the non-uniform equilibrium charge distribution on weak polyelectrolytes. For rigid rods, linearized density functional theory and simulation data show good agreement in a fairly wide parameter range. In the central part of the rod there appears a slight depletion of charge which is accumulated at the ends within a range of the order of the Debye length. For flexible chains, the simulations show an enhancement of the non-uniformity of the charge distribution.}, added-at = {2007-06-15T17:33:15.000+0200}, author = {Berghold, G. and van der Schoot, P. and Seidel, C.}, biburl = {https://www.bibsonomy.org/bibtex/2612856ebfc76c9370710c6d7c187ec52/kaigrass}, interhash = {e8287f99cc60a7ed8b5850a4c0d404a6}, intrahash = {612856ebfc76c9370710c6d7c187ec52}, journal = {J. Chem. Phys.}, keywords = {MC, PE charge distribution, for rigid rod theorie variational}, number = 19, pages = 8083, timestamp = {2007-06-15T17:33:17.000+0200}, title = {Equilibrium charge distribution on weak polyelectrolytes}, volume = 107, year = 1997 }