Article,

Temperature-dependent Raman scattering studies in CsLiSO4 and RbxCs(1-x)LiSO(4) (x=0.35)

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JOURNAL OF RAMAN SPECTROSCOPY, 32 (12): 1046-1051 (2001)
DOI: 10.1002/jrs.797

Abstract

Polarized Raman spectra of CsLiSO4 and RbxCs1-xLiSO4 (x = 0.35) were obtained for temperatures in the range 7-295 K. Several features observed in the spectra were interpreted in terms of the occurrence of phase transitions. Careful investigation of the x-ray and Raman spectra and a group theory analysis showed that although both crystals have the same room-temperature structure, the low-temperature phases adopted by CsLiSO4 and Rb0.35CS0.65LiSO4 are very different. Data from Raman measurements taken at 295 and 7 K were used to propose an assignment of the fundamental modes. Copyright (C) 2001 John Wiley Sons, Ltd.

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