Abstract
Polarized Raman spectra of CsLiSO4 and RbxCs1-xLiSO4 (x = 0.35) were
obtained for temperatures in the range 7-295 K. Several features
observed in the spectra were interpreted in terms of the occurrence of
phase transitions. Careful investigation of the x-ray and Raman spectra
and a group theory analysis showed that although both crystals have the
same room-temperature structure, the low-temperature phases adopted by
CsLiSO4 and Rb0.35CS0.65LiSO4 are very different. Data from Raman
measurements taken at 295 and 7 K were used to propose an assignment of
the fundamental modes. Copyright (C) 2001 John Wiley Sons, Ltd.
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