%0 Journal Article %1 1367-2630-15-2-025008 %A Albert, Julian %A Schubert, Alexander %A Engel, Volker %D 2013 %J New Journal of Physics %K ak-engel %N 2 %P 025008 %R https://doi.org/10.1088/1367-2630/15/2/025008 %T Two-dimensional vibronic spectroscopy of molecular predissociation %U http://stacks.iop.org/1367-2630/15/i=2/a=025008 %V 15 %X We calculate two-dimensional (2D) spectra reflecting the time-dependent electronic predissociation of a diatomic molecule. The laser-excited electronic state is coupled non-adiabatically to a fragment channel, leading to the decay of the prepared quasi-bound states. This decay can be monitored by the three-pulse configuration employed in optical 2D spectroscopy. It is shown that in this way it is possible to state-selectively characterize the time-dependent population of resonance states with different lifetimes. A model of the NaI molecule serves as a numerical example.

@article{1367-2630-15-2-025008, abstract = {We calculate two-dimensional (2D) spectra reflecting the time-dependent electronic predissociation of a diatomic molecule. The laser-excited electronic state is coupled non-adiabatically to a fragment channel, leading to the decay of the prepared quasi-bound states. This decay can be monitored by the three-pulse configuration employed in optical 2D spectroscopy. It is shown that in this way it is possible to state-selectively characterize the time-dependent population of resonance states with different lifetimes. A model of the NaI molecule serves as a numerical example.}, added-at = {2017-06-20T16:22:02.000+0200}, author = {Albert, Julian and Schubert, Alexander and Engel, Volker}, biburl = {https://www.bibsonomy.org/bibtex/273106f707813179a94c88d1bfe8c5b52/ak-engel-uniwue}, description = {Two-dimensional vibronic spectroscopy of molecular predissociation - IOPscience}, doi = {https://doi.org/10.1088/1367-2630/15/2/025008}, interhash = {00e707be3ba2dce325d1354db7e18dbe}, intrahash = {73106f707813179a94c88d1bfe8c5b52}, journal = {New Journal of Physics}, keywords = {ak-engel}, number = 2, pages = 025008, timestamp = {2019-07-18T11:56:52.000+0200}, title = {Two-dimensional vibronic spectroscopy of molecular predissociation}, url = {http://stacks.iop.org/1367-2630/15/i=2/a=025008}, volume = 15, year = 2013 }