%0 Journal Article %1 ISI:000248866700027 %A Mansouri, Ghobad %A Rezvani, Ali R. %A Hadadzadeh, Hassan %A Khavasi, Hamid Reza %A Saravani, Hamideh %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2007 %I ELSEVIER SCIENCE SA %J JOURNAL OF ORGANOMETALLIC CHEMISTRY %K 1,10-phenanthroline-5,6-dione; 2-phenylpyridine; complex; crystal cyclic cyclometalated structure; voltammetry} {Rh(III) %N 17 %P 3810-3815 %R 10.1016/j.jorganchem.2007.05.043 %T Cyclometalated rhodium(III) complex with phen-dione ligand %V 692 %X The novel cyclometalated Rh(III) complex, Rh(phpy-K-2 N, C-2 `)2(phen-dione)PF6, where phpy-K-2 N, C-2 ` is pyridine-2-yl-2-phenyl and phen-dione is 1,10-phenanthroline-5,6-dione has been prepared and characterized by elemental analysis, IR, H-1 NMR, and electronic absorption spectroscopies, cyclic voltammetry, and X-ray crystallography. The crystal structure of Rh(phpy-K-2 N C-2 `)2(phen-dione)PF6 center dot CH3CN shows that the coordination geometry around the Rh(111) is a distorted octahedron, with bite angles of 76.13 degrees-81.09 degrees for all three bidentate ligands. (c) 2007 Elsevier B.V. All rights reserved.

@article{ISI:000248866700027, abstract = {{The novel cyclometalated Rh(III) complex, {[}Rh(phpy-K-2 N, C-2 `)2(phen-dione)]PF6, where phpy-K-2 N, C-2 ` is pyridine-2-yl-2-phenyl and phen-dione is 1,10-phenanthroline-5,6-dione has been prepared and characterized by elemental analysis, IR, H-1 NMR, and electronic absorption spectroscopies, cyclic voltammetry, and X-ray crystallography. The crystal structure of {[}Rh(phpy-K-2 N C-2 `)2(phen-dione)]PF6 center dot CH3CN shows that the coordination geometry around the Rh(111) is a distorted octahedron, with bite angles of 76.13 degrees-81.09 degrees for all three bidentate ligands. (c) 2007 Elsevier B.V. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{PO BOX 564, 1001 LAUSANNE, SWITZERLAND}}, affiliation = {{Hadadzadeh, H (Reprint Author), Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran. Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran. Univ Sistan \& Baluchestan, Dept Chem, Zahedan, Iran. Shahid Beheshti Univ, Dept Chem, Tehran, Iran.}}, author = {Mansouri, Ghobad and Rezvani, Ali R. and Hadadzadeh, Hassan and Khavasi, Hamid Reza and Saravani, Hamideh}, author-email = {{hadad@cc.iut.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/22fe2d84b729eac0b637f7b4b2ce5ffec/hkhavasi}, cited-references = {{Adachi C, 2000, APPL PHYS LETT, V77, P904, DOI 10.1063/1.1306639. Aneetha H, 1997, J CHEM SOC DALTON, P1697, DOI 10.1039/a608194k. ARZ C, 1987, MAGN RESON CHEM, V25, P158, DOI 10.1002/mrc.1260250214. Balzani V, 1996, CHEM REV, V96, P759, DOI 10.1021/cr941154y. Barigelletti F, 2000, EUR J INORG CHEM, P113. Bennett MA, 2000, J ORGANOMET CHEM, V601, P299, DOI 10.1016/S0022-328X(00)00086-3. Berger S, 2004, INORG CHEM, V43, P1530, DOI 10.1021/ic0351388. Binnemans K, 2004, J MATER CHEM, V14, P191, DOI 10.1039/b311128h. Brissard M, 2001, EUR J INORG CHEM, P1745. Bruce D, 2002, ANAL CHEM, V74, P1340, DOI 10.1021/ac0111513. 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Chem.}}, keywords = {1,10-phenanthroline-5,6-dione; 2-phenylpyridine; complex; crystal cyclic cyclometalated structure; voltammetry} {Rh(III)}, keywords-plus = {{ORTHO-METALATED COMPLEXES; ELECTROCHEMICAL PROPERTIES; CRYSTAL-STRUCTURE; SPECTROSCOPIC PROPERTIES; RUTHENIUM COMPLEXES; RH(III) COMPLEXES; X-RAY; 1,10-PHENANTHROLINE-5,6-DIONE; LUMINESCENT; RECOGNITION}}, language = {{English}}, month = {{AUG 1}}, number = {{17}}, number-of-cited-references = {{65}}, pages = {{3810-3815}}, publisher = {{ELSEVIER SCIENCE SA}}, research-areas = {{Chemistry}}, times-cited = {{15}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Cyclometalated rhodium(III) complex with phen-dione ligand}}, type = {{Article}}, unique-id = {{ISI:000248866700027}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{4}}, volume = {{692}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Chemistry, Organic}}, year = {{2007}} }