%0 Journal Article %1 ISI:000331421400021 %A Golbedaghi, Reza %A Salehzadeh, Sadegh %A Khavasi, Hamid Reza %A Blackman, Allan G. %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2014 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K Binuclear Cocrystal} Di(binuclear); Macrocylic Schiff base complexes; ligands; {Manganese(II); %P 151-156 %R 10.1016/j.poly.2013.09.036 %T Mn(II) complexes of three 2+2 macrocyclic Schiff base ligands. Synthesis and X-ray crystal structure of the first binuclear-di(binuclear) cocrystal %V 68 %X The 2 + 2 cyclocondensation reactions of N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,2-diaminoethane (L-22py), N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,3-diaminopropane (L-23py) and N-(2-pyridylmethyl)-N-(3-aminopropyl)-1,3-diaminopropane (L-33py) with 2,6-diformyl-4-methylphenol (dfp) in the presence of MnCl2 4H(2)O in equimolar ratios are reported. The resulting compounds, (1), (2) and (3), respectively, were characterized by IR spectroscopy, elemental analysis and mass spectrometry. The X-ray crystal structure analysis of (3) showed that it contains a novel cocrystal of a binuclear Mn(II) macrocyclic cation and a di(binuclear) one. The Mn(II) ions in the latter binuclear and di(binuclear) cations are five and six-coordinate respectively. The two binuclear parts in the di(binuclear) cation are bonded through two bridging chloride ions. The macrocyclic ligand in the above cations also has two different conformational structures, but in both cases it catches a proton. The analytical data show that compounds (1) and (2) probably have similar structures to (3). (C) 2013 Elsevier Ltd. All rights reserved.

@article{ISI:000331421400021, abstract = {{The {[}2 + 2] cyclocondensation reactions of N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,2-diaminoethane (L-22py), N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,3-diaminopropane (L-23py) and N-(2-pyridylmethyl)-N-(3-aminopropyl)-1,3-diaminopropane (L-33py) with 2,6-diformyl-4-methylphenol (dfp) in the presence of MnCl2 4H(2)O in equimolar ratios are reported. The resulting compounds, (1), (2) and (3), respectively, were characterized by IR spectroscopy, elemental analysis and mass spectrometry. The X-ray crystal structure analysis of (3) showed that it contains a novel cocrystal of a binuclear Mn(II) macrocyclic cation and a di(binuclear) one. The Mn(II) ions in the latter binuclear and di(binuclear) cations are five and six-coordinate respectively. The two binuclear parts in the di(binuclear) cation are bonded through two bridging chloride ions. The macrocyclic ligand in the above cations also has two different conformational structures, but in both cases it catches a proton. The analytical data show that compounds (1) and (2) probably have similar structures to (3). (C) 2013 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Golbedaghi, R (Reprint Author), Payame Noor Univ, Dept Chem, Tehran 193954697, Iran. Golbedaghi, Reza, Payame Noor Univ, Dept Chem, Tehran 193954697, Iran. Salehzadeh, Sadegh, Bu Ali Sina Univ, Fac Chem, Hamadan, Iran. Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Blackman, Allan G., Univ Otago, Dept Chem, Dunedin, New Zealand.}}, author = {Golbedaghi, Reza and Salehzadeh, Sadegh and Khavasi, Hamid Reza and Blackman, Allan G.}, author-email = {{golbedaghi82@gmail.com}}, biburl = {https://www.bibsonomy.org/bibtex/2b53fee2961c825313d06d5ae62a2149e/hkhavasi}, cited-references = {{ADAMS H, 1995, J CHEM SOC DALTON, P275, DOI 10.1039/dt9950000275. Adhikari B.B., 2002, J CHEM SOC DA, P2760. Aono T, 1997, J CHEM SOC DALTON, P3029, DOI 10.1039/a702210g. Archibald SJ, 1997, J CHEM SOC DALTON, P173, DOI 10.1039/a605154e. Arion VB, 1998, INORG CHIM ACTA, V282, P61, DOI 10.1016/S0020-1693(98)00198-4. Atkins AJ, 1996, CHEM COMMUN, P457, DOI 10.1039/cc9960000457. Biswas P, 2006, INORG CHEM, V45, P4830, DOI 10.1021/ic060183b. Brandt CD, 2004, INORG CHIM ACTA, V357, P4265, DOI 10.1016/j.ica.2004.06.013. Brianese N, 1999, INORG CHIM ACTA, V293, P178, DOI 10.1016/S0020-1693(99)00235-2. Cheng TH, 2000, POLYHEDRON, V19, P2027, DOI 10.1016/S0277-5387(00)00502-7. 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Zhu LN, 2007, INORG CHEM, V46, P1297, DOI 10.1021/ic061792m. {[}Anonymous], 1995, INT TABLES XRAY CRYS, VC, P1121.}}, doc-delivery-number = {{AA9NY}}, doi = {{10.1016/j.poly.2013.09.036}}, funding-acknowledgement = {{Bu-Ali Sina University; Shahid Beheshti University; Otago University}}, funding-text = {{We are grateful to the Bu-Ali Sina, Shahid Beheshti and Otago Universities for financial support.}}, interhash = {c0ab4a1e72260d8a3811baaabd588681}, intrahash = {b53fee2961c825313d06d5ae62a2149e}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {Binuclear Cocrystal} Di(binuclear); Macrocylic Schiff base complexes; ligands; {Manganese(II);}, keywords-plus = {{MAGNETIC-PROPERTIES; PENDANT-ARM; MONONUCLEAR; COPPER(II); DINICKEL(II); CO; ELECTROCHEMISTRY; BARIUM(II); PLATFORMS; CU-4(II)}}, language = {{English}}, month = {{JAN 28}}, number-of-cited-references = {{58}}, pages = {{151-156}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{7}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Mn(II) complexes of three {[}2+2] macrocyclic Schiff base ligands. Synthesis and X-ray crystal structure of the first binuclear-di(binuclear) cocrystal}}, type = {{Article}}, unique-id = {{ISI:000331421400021}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{7}}, volume = {{68}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2014}} }