%0 Journal Article %1 WOS:000291421400007 %A Lima, Cleanio L %A Vasconcelos, Santiago J S %A Filho, Josue Mendes %A Viana, Bartolomeu C %A Rocha, Maria G C %A Bargiela, Pascal %A Oliveira, Alcineia C %C RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS %D 2011 %I ELSEVIER %J APPLIED CATALYSIS A-GENERAL %K Characterisations} Dehydration; Glycerol; Nanocasting; {Oxides; %N 1-2 %P 50-62 %R 10.1016/j.apcata.2011.03.036 %T Nanocasted oxides for gas phase glycerol conversion %V 399 %X Catalytic performance of binary nanostructured oxides has been evaluated in the gas-phase dehydration of glycerol, an environmental friendly reaction. SnO2-Mn2O3, SnO2-ZrO2, SnO2-TiO2, ZrO2-Mn2O3 nanocasted oxides, and a reference, NiO-Co3O4, were characterised by XRD, Raman spectroscopy, acid-base measurements, SEM-EDX, TPR, HTEM and XPS. Correlations among the catalyst's activity and the surface, textural, and acid-base properties of the nanocasted oxides were tentatively conducted in attempts to justify the catalytic results. Influences of nanoparticle or nanostructure structural properties on the catalytic activity have been investigated. The better activity of SnO2-TiO2 at 250 degrees C and a glycerol/water molar ratio of 0.25 was due to cooperativity of Sn4+ and Ti4+. The most important finding was that nanostructure features of the solid enhanced nanoparticle stability through the redox ability of the binary solid compared to conventional binary catalysts. (C) 2011 Elsevier B.V. All rights reserved.

@article{WOS:000291421400007, abstract = {Catalytic performance of binary nanostructured oxides has been evaluated in the gas-phase dehydration of glycerol, an environmental friendly reaction. SnO2-Mn2O3, SnO2-ZrO2, SnO2-TiO2, ZrO2-Mn2O3 nanocasted oxides, and a reference, NiO-Co3O4, were characterised by XRD, Raman spectroscopy, acid-base measurements, SEM-EDX, TPR, HTEM and XPS. Correlations among the catalyst's activity and the surface, textural, and acid-base properties of the nanocasted oxides were tentatively conducted in attempts to justify the catalytic results. Influences of nanoparticle or nanostructure structural properties on the catalytic activity have been investigated. The better activity of SnO2-TiO2 at 250 degrees C and a glycerol/water molar ratio of 0.25 was due to cooperativity of Sn4+ and Ti4+. The most important finding was that nanostructure features of the solid enhanced nanoparticle stability through the redox ability of the binary solid compared to conventional binary catalysts. (C) 2011 Elsevier B.V. All rights reserved.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS}, author = {Lima, Cleanio L and Vasconcelos, Santiago J S and Filho, Josue Mendes and Viana, Bartolomeu C and Rocha, Maria G C and Bargiela, Pascal and Oliveira, Alcineia C}, biburl = {https://www.bibsonomy.org/bibtex/2ccf7e1b99f8a42824d34fc21296277c3/ppgfis_ufc_br}, doi = {10.1016/j.apcata.2011.03.036}, interhash = {c5e6915ca4f8535f3df3f85116749bda}, intrahash = {ccf7e1b99f8a42824d34fc21296277c3}, issn = {0926-860X}, journal = {APPLIED CATALYSIS A-GENERAL}, keywords = {Characterisations} Dehydration; Glycerol; Nanocasting; {Oxides;}, number = {1-2}, pages = {50-62}, publisher = {ELSEVIER}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Nanocasted oxides for gas phase glycerol conversion}, tppubtype = {article}, volume = 399, year = 2011 }