%0 Journal Article %1 suss2019mapping %A Süß, J %A Wehner, J %A Dostál, J %A Brixner, T %A Engel, V %B The Journal of Chemical Physics %D 2019 %I American Institute of Physics %J J. Chem. Phys. %K for1809 grk2112 myown %N 10 %P 104304 %R 10.1063/1.5086151 %T Mapping of exciton–exciton annihilation in a molecular dimer via fifth-order femtosecond two-dimensional spectroscopy %U https://doi.org/10.1063/1.5086151 %V 150 %X We present a theoretical study on exciton–exciton annihilation (EEA) in a molecular dimer. This process is monitored using a fifth-order coherent two-dimensional (2D) spectroscopy as was recently proposed by Dostál et al. Nat. Commun. 9, 2466 (2018). Using an electronic three-level system for each monomer, we analyze the different paths which contribute to the 2D spectrum. The spectrum is determined by two entangled relaxation processes, namely, the EEA and the direct relaxation of higher lying excited states. It is shown that the change of the spectrum as a function of a pulse delay can be linked directly to the presence of the EEA process.

@article{suss2019mapping, abstract = {We present a theoretical study on exciton–exciton annihilation (EEA) in a molecular dimer. This process is monitored using a fifth-order coherent two-dimensional (2D) spectroscopy as was recently proposed by Dostál et al. [Nat. Commun. 9, 2466 (2018)]. Using an electronic three-level system for each monomer, we analyze the different paths which contribute to the 2D spectrum. The spectrum is determined by two entangled relaxation processes, namely, the EEA and the direct relaxation of higher lying excited states. It is shown that the change of the spectrum as a function of a pulse delay can be linked directly to the presence of the EEA process.}, added-at = {2019-03-19T09:33:39.000+0100}, author = {Süß, J and Wehner, J and Dostál, J and Brixner, T and Engel, V}, biburl = {https://www.bibsonomy.org/bibtex/2c493193c34b4ac8a110dad63afc5927d/ak-engel-uniwue}, booktitle = {The Journal of Chemical Physics}, comment = {doi: 10.1063/1.5086151}, doi = {10.1063/1.5086151}, interhash = {dec448962c42812e3edbaa09f5611c4a}, intrahash = {c493193c34b4ac8a110dad63afc5927d}, issn = {00219606}, journal = {J. Chem. Phys.}, keywords = {for1809 grk2112 myown}, month = mar, number = 10, pages = 104304, publisher = {American Institute of Physics}, timestamp = {2020-05-06T09:55:34.000+0200}, title = {Mapping of exciton–exciton annihilation in a molecular dimer via fifth-order femtosecond two-dimensional spectroscopy}, url = {https://doi.org/10.1063/1.5086151}, volume = 150, year = 2019 }