Article,
Tris(diisopropylammonium) hydrogensulfate sulfate
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64 (8): O1564-U2945 (August 2008)
DOI: {10.1107/S160053680802237X}
Abstract
The cations and anions of the title salt, 3C(6)H(16)N(+)center dot-HSO4
(-)center dot SO42-, are linked by N-H center dot center dot center dot
O and O-H center dot center dot center dot O hydrogen bonds into a
three-dimensional network. The hydrogensulfate ion, with a single S - O(
H) bond of 1.563 (2) angstrom, forms a short O-H center dot center dot
center dot O hydrogen bond O center dot center dot center dot O =
2.609 (2) angstrom to the sulfate ion. The hydrogensulfate ion accepts
two hydrogen bonds from two cations, whereas the sulfate ion, as an
acceptor, binds to four cations. The sulfate ion is disordered
approximately equally over two sites related by rotation around one of
the O - S bonds.
