%0 Journal Article %1 ISI:000254528300067 %A Sabounchei, Seyyed Javad %A Jodaian, Vida %A Khavasi, Hamid Reza %C 9600 GARSINGTON RD, OXFORD OX4 2DQ, OXON, ENGLAND %D 2008 %I BLACKWELL PUBLISHING %J ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE %K imported %N 4 %P O647-U780 %R 10.1107/S1600536808005497 %T 2-Thienylcarbonylmethylene-triphenylphosphorane ylide %V 64 %X In the molecule of the title compound, (2-thienylcarbonyl)(triphenylphosphonio) methanide, C24H19OPS, the geometry around the P atom is nearly tetrahedral and the O-C-C-P torsion angle is 2.80 (3)degrees. The thiophene ring is twisted through an angle of 4.33 (4)degrees with respect to the plane of the carbonyl group. Inter- and intramolecular hydrogen bonds and C-H center dot center dot center dot pi interactions are present in the crystal structure.

@article{ISI:000254528300067, abstract = {{In the molecule of the title compound, (2-thienylcarbonyl)(triphenylphosphonio) methanide, C24H19OPS, the geometry around the P atom is nearly tetrahedral and the O-C-C-P torsion angle is 2.80 (3)degrees. The thiophene ring is twisted through an angle of 4.33 (4)degrees with respect to the plane of the carbonyl group. Inter- and intramolecular hydrogen bonds and C-H center dot center dot center dot pi interactions are present in the crystal structure.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{9600 GARSINGTON RD, OXFORD OX4 2DQ, OXON, ENGLAND}}, affiliation = {{Sabounchei, SJ (Reprint Author), Bu Ali Sina Univ, Fac Chem, Hamadan 651714, Iran. Sabounchei, Seyyed Javad; Jodaian, Vida, Bu Ali Sina Univ, Fac Chem, Hamadan 651714, Iran. Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Sabounchei, Seyyed Javad and Jodaian, Vida and Khavasi, Hamid Reza}, author-email = {{jsabounchei@yahoo.co.uk}}, biburl = {https://www.bibsonomy.org/bibtex/21f3af69f5cffc884f20bff594a42bc38/hkhavasi}, cited-references = {{ALLEN FH, 1987, J CHEM SOC PERK T 2, pS1, DOI 10.1039/p298700000s1. BART JCJ, 1969, J CHEM SOC B, P350, DOI 10.1039/j29690000350. Dunitz J. D., 1979, XRAY ANAL STRUCTURE. Farrugia LJ, 1997, J APPL CRYSTALLOGR, V30, P565, DOI DOI 10.1107/S0021889897003117. Farrugia L. J., 1999, J APPL CRYSTALLOGR, V32, P837, DOI DOI 10.1107/S0021889899006020. FLACK HD, 1983, ACTA CRYSTALLOGR A, V39, P876, DOI 10.1107/S0108767383001762. Sheldrick GM, 2008, ACTA CRYSTALLOGR A, V64, P112, DOI 10.1107/S0108767307043930. {*}STOE CIE, 2005, X RED32 X AREA X SHA.}}, doc-delivery-number = {{281VZ}}, doi = {{10.1107/S1600536808005497}}, interhash = {f92c0f64750f45464fe5df266ab9d4e1}, intrahash = {1f3af69f5cffc884f20bff594a42bc38}, issn = {{1600-5368}}, journal = {{ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE}}, journal-iso = {{Acta Crystallogr. Sect. E.-Struct Rep. Online}}, keywords = {imported}, language = {{English}}, month = {{APR}}, number = {{4}}, number-of-cited-references = {{8}}, pages = {{O647-U780}}, publisher = {{BLACKWELL PUBLISHING}}, research-areas = {{Crystallography}}, times-cited = {{0}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{2-Thienylcarbonylmethylene-triphenylphosphorane ylide}}, type = {{Article}}, unique-id = {{ISI:000254528300067}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{2}}, volume = {{64}}, web-of-science-categories = {{Crystallography}}, year = {{2008}} }