%0 Journal Article %1 ISI:000253691100006 %A Azadmeher, Amirreza %A Amini, Mostafa M. %A Hadipour, Nasser %A Khavasi, Hamid Reza %A Fun, Hoong-Kun %A Chen, Chun-Jung %C THE ATRIUM, SOUTHERN GATE, CHICHESTER PO19 8SQ, W SUSSEX, ENGLAND %D 2008 %I JOHN WILEY & SONS LTD %J APPLIED ORGANOMETALLIC CHEMISTRY %K 2,6-pyridinedicarboxylic X-ray; acid; methoxide; potassium propoxide} sodium {organotin; %N 1 %P 19-24 %R 10.1002/aoc.1343 %T Synthesis and structural characterization of diorganotin(IV) complexes with 2,6-pyridinedicarboxylic acid %V 22 %X Two new diorganotin(IV) derivatives of 2,6-pyridinedicarboxylic acid, \Ph2Sn(2,6-C5H3N)(COO)(2)Na(2,6-C5H3N)(COOH) (COO)(CH3OH)(2)\ (1) and Me2Sn(2,6-C5H3N)(COO)(2)(H2O)center dot H2O (2) were synthesized by the reaction of Ph3SnCl and PhMe(2)Snl with 2,6-pyridinedicarboxylic acid, respectively in the presence of sodium methoxide or potassium iso-propoxide. The prepared compounds were characterized by mass spectrometry, IR, H-1, C-13 and Sn-119 NMR spectroscopies. The molecular structures of both complexes were determined by a single-crystal X-ray analysis. The X-ray structure revealed pentagonal bipyramidal geometry around the tin atom for compound 1, which is incorporated with a hexacoordinated monosodium derivative of 2,6-pyridinedicarboxylic acid. Complex 2 adopts a monomeric structure with two carboxylate oxygen atoms coordinated to tin in monodenate form from equatorial positions, and the coordination number is raised to six as the oxygen of water and pyridine nitrogen occupies the other equatorial positions of octahedron. Copyright (C) 2007 John Wiley & Sons, Ltd.

@article{ISI:000253691100006, abstract = {{Two new diorganotin(IV) derivatives of 2,6-pyridinedicarboxylic acid, \{{[}Ph2Sn(2,6-C5H3N)(COO)(2)]{[}Na(2,6-C5H3N)(COOH) (COO)(CH3OH)(2)]\} (1) and {[}Me2Sn(2,6-C5H3N)(COO)(2)(H2O)]center dot H2O (2) were synthesized by the reaction of Ph3SnCl and PhMe(2)Snl with 2,6-pyridinedicarboxylic acid, respectively in the presence of sodium methoxide or potassium iso-propoxide. The prepared compounds were characterized by mass spectrometry, IR, H-1, C-13 and Sn-119 NMR spectroscopies. The molecular structures of both complexes were determined by a single-crystal X-ray analysis. The X-ray structure revealed pentagonal bipyramidal geometry around the tin atom for compound 1, which is incorporated with a hexacoordinated monosodium derivative of 2,6-pyridinedicarboxylic acid. Complex 2 adopts a monomeric structure with two carboxylate oxygen atoms coordinated to tin in monodenate form from equatorial positions, and the coordination number is raised to six as the oxygen of water and pyridine nitrogen occupies the other equatorial positions of octahedron. Copyright (C) 2007 John Wiley \& Sons, Ltd.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE ATRIUM, SOUTHERN GATE, CHICHESTER PO19 8SQ, W SUSSEX, ENGLAND}}, affiliation = {{Amini, MM (Reprint Author), Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Azadmeher, Amirreza; Amini, Mostafa M.; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Hadipour, Nasser, Tarbiat Modares Univ, Dept Chem, Tehran, Iran. Fun, Hoong-Kun, Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia. Chen, Chun-Jung, Natl Synchrotron Radiat Res Ctr, Div Res, Hsinchu 30076, Taiwan.}}, author = {Azadmeher, Amirreza and Amini, Mostafa M. and Hadipour, Nasser and Khavasi, Hamid Reza and Fun, Hoong-Kun and Chen, Chun-Jung}, author-email = {{m-pouramini@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2164d2565b4ad90987ce1d2edd522bd0b/hkhavasi}, cited-references = {{Amini MM, 2007, ACTA CRYSTALLOGR E, V63, pm810, DOI 10.1107/S1600536807007295. {*}BRUK, 2004, APEX 2 VERS 1 27 SAI. Chandrasekhar V, 2005, COORDIN CHEM REV, V249, P1745, DOI 10.1016/j.ccr.2005.03.028. Costa LCM, 2005, SPECTROCHIM ACTA A, V61, P1971, DOI 10.1016/j.saa.2004.07.028. COSTA LCM, 2006, SOLID STATE COMMUN, V137, P76. DAVISON A, 1970, J ORGANOMET CHEM, V23, P407, DOI 10.1016/S0022-328X(00)92954-1. DEACON GB, 1980, COORDIN CHEM REV, V33, P227, DOI 10.1016/S0010-8545(00)80455-5. Gielen M, 2002, APPL ORGANOMET CHEM, V16, P481, DOI 10.1002/aoc.331. 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Stoe \& Cie, 2000, X STEP32 VERS 1 07B. Szorcsik A, 2004, J ORGANOMET CHEM, V689, P2762, DOI 10.1016/j.jorganchem..2004.05.045. TIEKINK ERT, 1991, APPL ORGANOMET CHEM, V5, P1, DOI 10.1002/aoc.590050102. TIEKINK ERT, 1994, TRENDS ORGANOMET CHE, V1, P74. Willem R, 1998, ORGANOMETALLICS, V17, P5758, DOI 10.1021/om980504u. WILLEM R, 1993, APPL ORGANOMET CHEM, V7, P311, DOI 10.1002/aoc.590070504.}}, doc-delivery-number = {{270AC}}, doi = {{10.1002/aoc.1343}}, interhash = {f71fc065a71093a4d23f6a536bcf02b1}, intrahash = {164d2565b4ad90987ce1d2edd522bd0b}, issn = {{0268-2605}}, journal = {{APPLIED ORGANOMETALLIC CHEMISTRY}}, journal-iso = {{Appl. Organomet. Chem.}}, keywords = {2,6-pyridinedicarboxylic X-ray; acid; methoxide; potassium propoxide} sodium {organotin;}, keywords-plus = {{VITRO ANTITUMOR-ACTIVITY; ORGANOTIN CARBOXYLATES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; DERIVATIVES; CHEMISTRY; NMR; TRIORGANOTIN}}, language = {{English}}, month = {{JAN}}, number = {{1}}, number-of-cited-references = {{31}}, orcid-numbers = {{Chen, Chun-Jung/0000-0002-5157-4288}}, pages = {{19-24}}, publisher = {{JOHN WILEY \& SONS LTD}}, research-areas = {{Chemistry}}, researcherid-numbers = {{Fun, Hoong-Kun/A-3561-2009 Chen, Chun-Jung/A-6880-2011}}, times-cited = {{19}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and structural characterization of diorganotin(IV) complexes with 2,6-pyridinedicarboxylic acid}}, type = {{Article}}, unique-id = {{ISI:000253691100006}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{9}}, volume = {{22}}, web-of-science-categories = {{Chemistry, Applied; Chemistry, Inorganic \& Nuclear}}, year = {{2008}} }