Adsorption of CO and O2 on Pd particles deposited on a well-ordered
Fe3O4(111) film was studied by temperature programmed desorption.
Scanning tunneling microscopy was used to provide structural information.
The results show that CO adsorbed on Pd particles reacts with oxygen
of the oxide support and forms CO2. The reaction occurs at the particle/oxide
interface and exhibits a particle size effect such that the smaller
particles produce more CO2. Oxidation of Pd/Fe3O4 alters the oxide
structure due to Pd catalyzed oxygen migration into the film and
results in formation of an oxygen reservoir, which favors CO oxidation
reaction.
%0 Journal Article
%1 Meyer2004
%A Meyer, R.
%A Shaikhutdinov, S. K.
%A Freund, H.-J.
%D 2004
%J Z. Phys. Chem.
%K particle, science surface
%P 905-914
%R 10.1524/zpch.218.8.905.35983
%T CO Oxidation on a Pd/Fe3O4(111) Model Catalyst
%V 218
%X Adsorption of CO and O2 on Pd particles deposited on a well-ordered
Fe3O4(111) film was studied by temperature programmed desorption.
Scanning tunneling microscopy was used to provide structural information.
The results show that CO adsorbed on Pd particles reacts with oxygen
of the oxide support and forms CO2. The reaction occurs at the particle/oxide
interface and exhibits a particle size effect such that the smaller
particles produce more CO2. Oxidation of Pd/Fe3O4 alters the oxide
structure due to Pd catalyzed oxygen migration into the film and
results in formation of an oxygen reservoir, which favors CO oxidation
reaction.
@article{Meyer2004,
abstract = {Adsorption of CO and O2 on Pd particles deposited on a well-ordered
Fe3O4(111) film was studied by temperature programmed desorption.
Scanning tunneling microscopy was used to provide structural information.
The results show that CO adsorbed on Pd particles reacts with oxygen
of the oxide support and forms CO2. The reaction occurs at the particle/oxide
interface and exhibits a particle size effect such that the smaller
particles produce more CO2. Oxidation of Pd/Fe3O4 alters the oxide
structure due to Pd catalyzed oxygen migration into the film and
results in formation of an oxygen reservoir, which favors CO oxidation
reaction.},
added-at = {2009-10-30T10:04:05.000+0100},
author = {Meyer, R. and Shaikhutdinov, S. K. and Freund, H.-J.},
biburl = {https://www.bibsonomy.org/bibtex/23d092d08ed5204c423d7b12fcb95ed68/jfischer},
doi = {10.1524/zpch.218.8.905.35983},
interhash = {07868df0af9cbecbe9a2b60227332cc3},
intrahash = {3d092d08ed5204c423d7b12fcb95ed68},
journal = {Z. Phys. Chem.},
keywords = {particle, science surface},
pages = {905-914},
timestamp = {2009-10-30T10:04:17.000+0100},
title = {CO Oxidation on a Pd/Fe3O4(111) Model Catalyst},
volume = 218,
year = 2004
}