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Spontaneous breaking of time-reversal symmetry in the pseudogap state of a high-Tc superconductor

, , , , , , , , , , and . Nature, 416 (6881): 610--613 (April 2002)

Abstract

A change in 'symmetry' is often observed when matter undergoes a phase transition—the symmetry is said to be spontaneously broken. The transition made by underdoped high-transition-temperature (high-$T_c$) superconductors is unusual, in that it is not a mean-field transition as seen in other superconductors. Rather, there is a region in the phase diagram above the superconducting transition temperature $T_c$ (where phase coherence and superconductivity begin) but below a characteristic temperature $T*$ where a 'pseudogap' appears in the spectrum of electronic excitations$^1, 2$. It is therefore important to establish if $T*$ is just a cross-over temperature arising from fluctuations in the order parameter that will establish superconductivity at $T_c$ (refs 3, 4), or if it marks a phase transition where symmetry is spontaneously broken$^5, 6, 7, 8, 9, 10$. Here we report that, for a material in the pseudogap state, left-circularly polarized photons give a different photocurrent from right-circularly polarized photons. This shows that time-reversal symmetry is spontaneously broken$^11$ below $T*$, which therefore corresponds to a phase transition.

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