OH RADICAL REACTION-RATE CONSTANTS FOR POLYCYCLIC ALKANES - EFFECTS OF RING STRAIN AND CONSEQUENCES FOR ESTIMATION METHODS
R. Atkinson, and S. ASCHMANN. International Journal of Chemical Kinetics, 24 (11):
983--989(January 1992)
Abstract
Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with trans-pinane (1R,2R)-2, 6, 6-trimethylbicyclo3.1.1heptane, tricyclene (1, 7, 7-trimethyltricyclo2.2.1.0(2,6)heptane), and quadricyclane (quadricyclo-2.2.1.0(2,6).0(3,5)heptane) of (1.34 +/- 0.29) X 10(-11) cm3 molecule-1 s-1, (2.86 +/- 0.62) X 10(-12) cm3 molecule-1 s-1 and (1.83 +/- 0.41) X 10(-12) cm3 molecule-1 s-1, respectively, have been determined at 296 +/- 2 K. These rate constants are compared with values calculated from an empirical estimation method and used to refine this estimation technique for the calculation of OH radical reaction rate constants for polycyclic systems.
%0 Journal Article
%1 Atkinson:1992p3736
%A Atkinson, R
%A ASCHMANN, SM
%D 1992
%J International Journal of Chemical Kinetics
%K Gas-Phase Organic-Compounds, Reactions
%N 11
%P 983--989
%T OH RADICAL REACTION-RATE CONSTANTS FOR POLYCYCLIC ALKANES - EFFECTS OF RING STRAIN AND CONSEQUENCES FOR ESTIMATION METHODS
%U http://www.google.com/search?client=safari&rls=en-us&q=OH+RADICAL+REACTION-RATE+CONSTANTS+FOR+POLYCYCLIC+ALKANES+-+EFFECTS+OF+RING+STRAIN+AND+CONSEQUENCES+FOR+ESTIMATION+METHODS&ie=UTF-8&oe=UTF-8
%V 24
%X Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with trans-pinane (1R,2R)-2, 6, 6-trimethylbicyclo3.1.1heptane, tricyclene (1, 7, 7-trimethyltricyclo2.2.1.0(2,6)heptane), and quadricyclane (quadricyclo-2.2.1.0(2,6).0(3,5)heptane) of (1.34 +/- 0.29) X 10(-11) cm3 molecule-1 s-1, (2.86 +/- 0.62) X 10(-12) cm3 molecule-1 s-1 and (1.83 +/- 0.41) X 10(-12) cm3 molecule-1 s-1, respectively, have been determined at 296 +/- 2 K. These rate constants are compared with values calculated from an empirical estimation method and used to refine this estimation technique for the calculation of OH radical reaction rate constants for polycyclic systems.
@article{Atkinson:1992p3736,
abstract = {Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with trans-pinane [(1R,2R)-2, 6, 6-trimethylbicyclo[3.1.1]heptane], tricyclene (1, 7, 7-trimethyltricyclo[2.2.1.0(2,6)]heptane), and quadricyclane (quadricyclo-[2.2.1.0(2,6).0(3,5)]heptane) of (1.34 +/- 0.29) X 10(-11) cm3 molecule-1 s-1, (2.86 +/- 0.62) X 10(-12) cm3 molecule-1 s-1 and (1.83 +/- 0.41) X 10(-12) cm3 molecule-1 s-1, respectively, have been determined at 296 +/- 2 K. These rate constants are compared with values calculated from an empirical estimation method and used to refine this estimation technique for the calculation of OH radical reaction rate constants for polycyclic systems.},
added-at = {2010-06-22T19:38:37.000+0200},
affiliation = {UNIV CALIF RIVERSIDE,DEPT SOIL {\&} ENVIRONM SCI,RIVERSIDE,CA 92521},
author = {Atkinson, R and ASCHMANN, SM},
biburl = {https://www.bibsonomy.org/bibtex/2673902fdbf230c016fe2159fb0b82db3/gsmith},
date-added = {2010-05-07 12:32:49 -0400},
date-modified = {2010-05-07 12:33:13 -0400},
interhash = {b95ecd8e8150353c82573414d437c5df},
intrahash = {673902fdbf230c016fe2159fb0b82db3},
journal = {International Journal of Chemical Kinetics},
keywords = {Gas-Phase Organic-Compounds, Reactions},
language = {English},
month = Jan,
number = 11,
pages = {983--989},
pmid = {A1992JT52600007},
rating = {0},
timestamp = {2010-06-22T19:39:25.000+0200},
title = {OH RADICAL REACTION-RATE CONSTANTS FOR POLYCYCLIC ALKANES - EFFECTS OF RING STRAIN AND CONSEQUENCES FOR ESTIMATION METHODS},
uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3736},
url = {http://www.google.com/search?client=safari&rls=en-us&q=OH+RADICAL+REACTION-RATE+CONSTANTS+FOR+POLYCYCLIC+ALKANES+-+EFFECTS+OF+RING+STRAIN+AND+CONSEQUENCES+FOR+ESTIMATION+METHODS&ie=UTF-8&oe=UTF-8},
volume = 24,
year = 1992
}