Article,

Brownian motion in a field of force and the diffusion model of chemical reactions

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Physica, 7 (4): 284 - 304 (1940)
DOI: https://doi.org/10.1016/S0031-8914(40)90098-2

Abstract

A particle which is caught in a potential hole and which, through the shuttling action of Brownian motion, can escape over a potential barrier yields a suitable model for elucidating the applicability of the transition state method for calculating the rate of chemical reactions.

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