%0 Journal Article %1 WOS:000425494200066 %A Nonato, A %A Yanez-Vilar, S %A Sanchez-Andujar, M %A Mira, J %A Senaris-Rodriguez, M A %A Paschoal, C W A %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2018 %I ELSEVIER SCIENCE SA %J JOURNAL OF ALLOYS AND COMPOUNDS %K CaMn7O12; Magnetoelectric; Quad-perovskites; XANES} {Multiferroic; %P 559-566 %R 10.1016/j.jallcom.2017.11.260 %T Impact of Co-doping on the structural and magnetic properties of multiferroic CaMn7O12 %V 740 %X In this manuscript we showed that Co-doping into CaMn7O12 (CMO) induces charge disordering between Mn3+ and Mn4+ ions into the B site in the perovskite structure leading to a cubic structure Im (3) over bar. Both antiferromagnetic transitions at T-N1 and T-N2 previously observed in CMO are strongly influenced by Co-doping. The transition at T-N1 disappears due to the structural disorder due to the Co doping, while that one at T-N2 occurs at high temperatures. Our magnetic results explained the role of Co-doping on the magnetic ordering of CMO. Since this magnetic ordering drives the induced electric polarization in such compound, the Co doping comes up as a simple way to tune the coupling between electric polarization and magnetic helix in CMO. (C) 2017 Elsevier B.V. All rights reserved.

@article{WOS:000425494200066, abstract = {In this manuscript we showed that Co-doping into CaMn7O12 (CMO) induces charge disordering between Mn3+ and Mn4+ ions into the B site in the perovskite structure leading to a cubic structure Im (3) over bar. Both antiferromagnetic transitions at T-N1 and T-N2 previously observed in CMO are strongly influenced by Co-doping. The transition at T-N1 disappears due to the structural disorder due to the Co doping, while that one at T-N2 occurs at high temperatures. Our magnetic results explained the role of Co-doping on the magnetic ordering of CMO. Since this magnetic ordering drives the induced electric polarization in such compound, the Co doping comes up as a simple way to tune the coupling between electric polarization and magnetic helix in CMO. (C) 2017 Elsevier B.V. All rights reserved.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {PO BOX 564, 1001 LAUSANNE, SWITZERLAND}, author = {Nonato, A and Yanez-Vilar, S and Sanchez-Andujar, M and Mira, J and Senaris-Rodriguez, M A and Paschoal, C W A}, biburl = {https://www.bibsonomy.org/bibtex/2d8da8c9c96924fea95641b7fe0057802/ppgfis_ufc_br}, doi = {10.1016/j.jallcom.2017.11.260}, interhash = {31bd2ad0091eb471a97745517fd396ce}, intrahash = {d8da8c9c96924fea95641b7fe0057802}, issn = {0925-8388}, journal = {JOURNAL OF ALLOYS AND COMPOUNDS}, keywords = {CaMn7O12; Magnetoelectric; Quad-perovskites; XANES} {Multiferroic;}, pages = {559-566}, publisher = {ELSEVIER SCIENCE SA}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Impact of Co-doping on the structural and magnetic properties of multiferroic CaMn7O12}, tppubtype = {article}, volume = 740, year = 2018 }