%0 Journal Article %1 ISI:000251617600025 %A Khanmohammadi, Hamid %A Arabahmadi, Razyeh %A Abnosi, Mohammad H. %A Khavasi, Hamid R. %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2007 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K Schiff base; biological complexes; crystal heterodinuclear structure} studies; {macrocyclicl; %N 17 %P 4963-4970 %R 10.1016/j.poly.2007.07.018 %T Synthesis, crystal structure, spectral and biological studies of Cu-II-M-II(M = Zn and Pb) heterodinuclear complexes of new phenol-based macrocyclic ligands %V 26 %X Eight new heterodinuclear Cu(II)-M(II) (M = Pb and Zn) complexes of four new phenol based compartmental macrocyclic ligands, possessing contiguous (N2O2) and (NxO2) (x = 2, 3) coordination sites, were prepared by the template reaction of N,N'-bis(3-formyl-5-ethylsalicylidene)ethane-1,2- diaminatocopper(II), with various di- and/or tri-amines in the presence of Pb(II) and Zn(II) ions. The crystal structure of CuZnL3(H2O)(CiO(4))(2), 6, was determined by X-ray diffraction and shows that the Zn(II) and Cu(II) ions reside in the N2O2 sites of the macrocyclic ligand. The fifth coordination site of the Zn centre is occupied by a water ligand. All the complexes have been characterized by elemental analysis, molar conductivity and spectroscopic methods IR and UV). Also, all the synthesized complexes were screened for their antibacterial and antiftingal activity against Escherichia coli, Staphyloccocus aureus and Candida albicans. (C) 2007 Elsevier Ltd. All rights reserved.

@article{ISI:000251617600025, abstract = {{Eight new heterodinuclear Cu(II)-M(II) (M = Pb and Zn) complexes of four new phenol based compartmental macrocyclic ligands, possessing contiguous (N2O2) and (NxO2) (x = 2, 3) coordination sites, were prepared by the template reaction of {[}N,N'-bis(3-formyl-5-ethylsalicylidene)ethane-1,2- diaminato]copper(II), with various di- and/or tri-amines in the presence of Pb(II) and Zn(II) ions. The crystal structure of {[}CuZnL3(H2O)](CiO(4))(2), 6, was determined by X-ray diffraction and shows that the Zn(II) and Cu(II) ions reside in the N2O2 sites of the macrocyclic ligand. The fifth coordination site of the Zn centre is occupied by a water ligand. All the complexes have been characterized by elemental analysis, molar conductivity and spectroscopic methods IR and UV). Also, all the synthesized complexes were screened for their antibacterial and antiftingal activity against Escherichia coli, Staphyloccocus aureus and Candida albicans. (C) 2007 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Khanmohammadi, H (Reprint Author), Arak Univ, Dept Chem, Arak 38156, Iran. Khanmohammadi, Hamid; Arabahmadi, Razyeh, Arak Univ, Dept Chem, Arak 38156, Iran. Abnosi, Mohammad H., Arak Univ, Dept Biol, Arak 38156, Iran. Khavasi, Hamid R., Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Khanmohammadi, Hamid and Arabahmadi, Razyeh and Abnosi, Mohammad H. and Khavasi, Hamid R.}, author-email = {{h-khanmohammadi@araku.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/24a34cc7d89502723e94701dcc4782f47/hkhavasi}, cited-references = {{Abe K, 2002, INORG CHEM, V41, P4461, DOI 10.1021/ic020002f. Agh-Atabay NM, 2005, EUR J MED CHEM, V40, P1096, DOI 10.1016/j.ejmech.2005.05.006. Biswas P, 2006, INORG CHEM, V45, P4830, DOI 10.1021/ic060183b. 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Yonemura M, 2002, INORG CHEM, V41, P582, DOI 10.1021/ic010499d.}}, doc-delivery-number = {{240VZ}}, doi = {{10.1016/j.poly.2007.07.018}}, interhash = {427b2bd8eb979a3aad4fd2e6781d4f39}, intrahash = {4a34cc7d89502723e94701dcc4782f47}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {Schiff base; biological complexes; crystal heterodinuclear structure} studies; {macrocyclicl;}, keywords-plus = {{COMPARTMENTAL LIGANDS; DINUCLEAR COMPLEXES; MAGNETIC-PROPERTIES; CO(SALEN) ENTITY; METAL-COMPLEXES; CO COMPLEXES; ANTIMICROBIAL ACTIVITY; COPPER(II) COMPLEXES; BINUCLEAR COPPER(II); HOMO-DINUCLEAR}}, language = {{English}}, month = {{OCT 30}}, number = {{17}}, number-of-cited-references = {{51}}, orcid-numbers = {{Khanmohammadi, Hamid/0000-0001-5600-4738}}, pages = {{4963-4970}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, researcherid-numbers = {{Khanmohammadi, Hamid/F-6339-2016}}, times-cited = {{5}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, crystal structure, spectral and biological studies of Cu-II-M-II(M = Zn and Pb) heterodinuclear complexes of new phenol-based macrocyclic ligands}}, type = {{Article}}, unique-id = {{ISI:000251617600025}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{4}}, volume = {{26}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2007}} }