%0 Journal Article %1 RN302 %A Castillo, C. %A Buono-Core, G. %A Manzur, C. %A Yutronic, N. %A Sierpe, R. %A Cabello, G. %A Chornik, B. %D 2016 %J Journal of the Chilean Chemical Society %K catalysis, diffraction, dqcauchile films, moo3, nanostructures, optical-properties, oxidation, oxide-films, oxides, photoelectron resonance, selective size, spectroscopy, sputtering, support, surface-plasmon temperature, thin x-ray xps %N 1 %P 2816-2820 %R 10.4067/S0717-97072016000100014 %T Molybdenum Trioxide Thin Films Doped with Gold Nanoparticles Grown by a Sequential Methodology: Photochemical Metal-Organic Deposition (Pmod) and Dc-Magnetron Sputtering %U /brokenurl#<Go to ISI>://WOS:000378145500014 %V 61 %X Gold nanoparticles (AuNPs) were deposited by DC-magnetron sputtering onto molybdenum trioxide (MoO3) thin films grown by Photochemical Metal-Organic Deposition (PMOD) on Si(100) and borosilicate glass substrates. The chemical, optical and morphology properties of the films were studied by UV/Vis Spectroscopy, Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD). SEM revealed that AuNPs formed after 5 s of sputtering. AuNPs are spherical and have both an average diameter of 18 nm and a relatively narrow size distribution. As the deposition time increases, larger structures are formed by an aggregation of AuNPs. XPS studies of the AuNP/MoO3 films on Si(100) showed the presence of Mo(VI) and Mo(V), which indicated that the films were primarily non-stoichiometric molybdenum oxides. The occurrence of oxygen vacancies in the substrate play an important role to stabilize the AuNPs.

@article{RN302, abstract = {Gold nanoparticles (AuNPs) were deposited by DC-magnetron sputtering onto molybdenum trioxide (MoO3) thin films grown by Photochemical Metal-Organic Deposition (PMOD) on Si(100) and borosilicate glass substrates. The chemical, optical and morphology properties of the films were studied by UV/Vis Spectroscopy, Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD). SEM revealed that AuNPs formed after 5 s of sputtering. AuNPs are spherical and have both an average diameter of 18 nm and a relatively narrow size distribution. As the deposition time increases, larger structures are formed by an aggregation of AuNPs. XPS studies of the AuNP/MoO3 films on Si(100) showed the presence of Mo(VI) and Mo(V), which indicated that the films were primarily non-stoichiometric molybdenum oxides. The occurrence of oxygen vacancies in the substrate play an important role to stabilize the AuNPs.}, added-at = {2019-12-04T03:57:35.000+0100}, author = {Castillo, C. and Buono-Core, G. and Manzur, C. and Yutronic, N. and Sierpe, R. and Cabello, G. and Chornik, B.}, biburl = {https://www.bibsonomy.org/bibtex/28008635e8c2e4badaee1dee63b924469/dqcauchile}, doi = {10.4067/S0717-97072016000100014}, interhash = {4b32323d8005a1a777d1750ffe776e04}, intrahash = {8008635e8c2e4badaee1dee63b924469}, issn = {0717-9707}, journal = {Journal of the Chilean Chemical Society}, keywords = {catalysis, diffraction, dqcauchile films, moo3, nanostructures, optical-properties, oxidation, oxide-films, oxides, photoelectron resonance, selective size, spectroscopy, sputtering, support, surface-plasmon temperature, thin x-ray xps}, number = 1, pages = {2816-2820}, timestamp = {2019-12-04T03:58:17.000+0100}, title = {Molybdenum Trioxide Thin Films Doped with Gold Nanoparticles Grown by a Sequential Methodology: Photochemical Metal-Organic Deposition (Pmod) and Dc-Magnetron Sputtering}, type = {Journal Article}, url = {/brokenurl#<Go to ISI>://WOS:000378145500014}, volume = 61, year = 2016 }