%0 Journal Article %1 WOS:000290133700019 %A Vasconcelos, Santiago J S %A Lima, Cleanio L %A Filho, Josue Mendes %A Oliveira, Alcemira C %A Barros, Eduardo B %A de Sousa, Francisco F %A Rocha, Maria G C %A Bargiela, Pascal %A Oliveira, Alcineia C %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2011 %I ELSEVIER SCIENCE SA %J CHEMICAL ENGINEERING JOURNAL %K Catalyst; Characterisation} Dehydration; Glycerol; Raman; oxides; {Nanocasted %N 2 %P 656-664 %R 10.1016/j.cej.2011.01.053 %T Activity of nanocasted oxides for gas-phase dehydration of glycerol %V 168 %X A series of nanocasted oxides were synthesised, and an analysis using basicity measurements provided evidence that low strength basic sites with high accessibility favoured the production of 1-hydroxyacetone from glycerol dehydration. Among the oxides studied (e.g., CeO2. ZrO2, and TiO2). the best results were obtained for a CeO2-ZrO2 binary oxide (activity = 3 x 10(-6) mmol g(-1) h(-1)), which revealed that a moderate basicity allowed acid-base cooperativity in the Ce08Zr0.2O2 phase to produce 1-hydroxyacetone. Indeed, TEM, Raman, XPS and SEM-EDX analyses and textural properties showed that these features influenced the activity of the catalyst towards glycerol conversion by preventing coking. (C) 2011 Elsevier B.V. All rights reserved.

@article{WOS:000290133700019, abstract = {A series of nanocasted oxides were synthesised, and an analysis using basicity measurements provided evidence that low strength basic sites with high accessibility favoured the production of 1-hydroxyacetone from glycerol dehydration. Among the oxides studied (e.g., CeO2. ZrO2, and TiO2). the best results were obtained for a CeO2-ZrO2 binary oxide (activity = 3 x 10(-6) mmol g(-1) h(-1)), which revealed that a moderate basicity allowed acid-base cooperativity in the Ce08Zr0.2O2 phase to produce 1-hydroxyacetone. Indeed, TEM, Raman, XPS and SEM-EDX analyses and textural properties showed that these features influenced the activity of the catalyst towards glycerol conversion by preventing coking. (C) 2011 Elsevier B.V. All rights reserved.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {PO BOX 564, 1001 LAUSANNE, SWITZERLAND}, author = {Vasconcelos, Santiago J S and Lima, Cleanio L and Filho, Josue Mendes and Oliveira, Alcemira C and Barros, Eduardo B and de Sousa, Francisco F and Rocha, Maria G C and Bargiela, Pascal and Oliveira, Alcineia C}, biburl = {https://www.bibsonomy.org/bibtex/23b739e0abe1f59fffd6a7ff7cc6d4034/ppgfis_ufc_br}, doi = {10.1016/j.cej.2011.01.053}, interhash = {520bee71fb13e0096079ea652166774e}, intrahash = {3b739e0abe1f59fffd6a7ff7cc6d4034}, issn = {1385-8947}, journal = {CHEMICAL ENGINEERING JOURNAL}, keywords = {Catalyst; Characterisation} Dehydration; Glycerol; Raman; oxides; {Nanocasted}, number = 2, pages = {656-664}, publisher = {ELSEVIER SCIENCE SA}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Activity of nanocasted oxides for gas-phase dehydration of glycerol}, tppubtype = {article}, volume = 168, year = 2011 }