%0 Journal Article %1 ISI:000396518100004 %A Amini, Mostafa M. %A Najafi, Ezzatollah %A Karami, Behzad %A Khavasi, Hamidreza %C 530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA %D 2017 %I TAYLOR & FRANCIS INC %J SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY %K (IV) SnO2 complex; nanoparticle} organotin photoluminescence; structure; {Crystal %N 3 %P 332-339 %R 10.1080/15533174.2016.1186051 %T Synthesis and characterization of a new organotin(IV) complex as a new precursor for preparation SnO2 nanoparticles %V 47 %X An efficient method was developed for the preparation of a new hexaorganostannoxane complex, Me(12)Sn(6)C(l)2(N-3)(2)(DMSO)(2)O-4 (1). The prepared complex was characterized by infrared, H-1, C-13, and Sn-119 NMR spectroscopes and elemental analysis. The structure of 1 was determined by single-crystal X-ray diffraction. Complex 1 was utilized as a precursor for the preparation of SnO2 nanoparticles by direct thermal decomposition at 500 degrees C in air. The nanostructure of SnO2 was characterized by scanning electron microscopy and X-ray powder diffraction. The SnO2 core showed a band gap of similar to 3.91 eV. The SnO2 nanoparticles show stable photoluminescence (PL) with an emission centered at 561 nm.

@article{ISI:000396518100004, abstract = {{An efficient method was developed for the preparation of a new hexaorganostannoxane complex, {[}Me(12)Sn(6)C(l)2(N-3)(2)(DMSO)(2)O-4] (1). The prepared complex was characterized by infrared, H-1, C-13, and Sn-119 NMR spectroscopes and elemental analysis. The structure of 1 was determined by single-crystal X-ray diffraction. Complex 1 was utilized as a precursor for the preparation of SnO2 nanoparticles by direct thermal decomposition at 500 degrees C in air. The nanostructure of SnO2 was characterized by scanning electron microscopy and X-ray powder diffraction. The SnO2 core showed a band gap of similar to 3.91 eV. The SnO2 nanoparticles show stable photoluminescence (PL) with an emission centered at 561 nm.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA}}, affiliation = {{Amini, MM (Reprint Author), Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Najafi, E (Reprint Author), Payame Noor Univ, Dept Chem, Tehran 193953697, Iran. Amini, Mostafa M.; Khavasi, Hamidreza, Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Najafi, Ezzatollah; Karami, Behzad, Payame Noor Univ, Dept Chem, Tehran 193953697, Iran.}}, author = {Amini, Mostafa M. and Najafi, Ezzatollah and Karami, Behzad and Khavasi, Hamidreza}, author-email = {{m-pouramini@sbu.ac.ir ezzat.najafi@gmail.com}}, biburl = {https://www.bibsonomy.org/bibtex/26b9969266aa1a4dc4eff7fdb5bb3ddb8/hkhavasi}, cited-references = {{ALLESTON DL, 1963, J CHEM SOC, P5469, DOI 10.1039/jr9630005469. Bagheri M, 2013, SENSOR ACTUAT B-CHEM, V188, P45, DOI 10.1016/j.snb.2013.06.069. Baumeister U, 2002, MAIN GROUP MET CHEM, V25, P521. Bruker, 2008, APEX2 SAINT. BRUS LE, 1983, J CHEM PHYS, V79, P5566, DOI 10.1063/1.445676. Cahours A., 1860, LIEBIGS ANN CHEM, V114, P354. Cahours A., 1860, LIEBIGS ANN CHEM, V62, P354. CLARK RJH, 1968, J CHEM SOC A, P1828, DOI 10.1039/j19680001828. 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Zhu JJ, 2000, CHEM MATER, V12, P2557, DOI 10.1021/cm9906831.}}, doc-delivery-number = {{EO2HV}}, doi = {{10.1080/15533174.2016.1186051}}, eissn = {{1553-3182}}, funding-acknowledgement = {{Vice-President's Office for Research Affairs of Shahid Beheshti University}}, funding-text = {{The authors thank the Vice-President's Office for Research Affairs of Shahid Beheshti University for supporting this work.}}, interhash = {83d1098fc81bf723bb75fe7feb149b90}, intrahash = {6b9969266aa1a4dc4eff7fdb5bb3ddb8}, issn = {{1553-3174}}, journal = {{SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY}}, journal-iso = {{Synth. React. Inorg. Met.-Org. Nano-Metal Chem.}}, keywords = {(IV) SnO2 complex; nanoparticle} organotin photoluminescence; structure; {Crystal}, keywords-plus = {{METAL-ORGANIC FRAMEWORKS; MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURE; PHOTOLUMINESCENCE; DISTANNOXANES; SPECTROSCOPY; CHEMISTRY; LIGANDS; SENSORS; DONOR}}, language = {{English}}, number = {{3}}, number-of-cited-references = {{51}}, pages = {{332-339}}, publisher = {{TAYLOR \& FRANCIS INC}}, research-areas = {{Chemistry; Science \& Technology - Other Topics}}, times-cited = {{0}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and characterization of a new organotin(IV) complex as a new precursor for preparation SnO2 nanoparticles}}, type = {{Article}}, unique-id = {{ISI:000396518100004}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{1}}, volume = {{47}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Nanoscience \& Nanotechnology}}, year = {{2017}} }