%0 Journal Article %1 Friese2008 %A Friese, Viviane A. %A Kurth, Dirk G. %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2008 %I ELSEVIER SCIENCE SA %J COORDINATION CHEMISTRY REVIEWS %K dgkurth %N 1-2 %P 199-211 %R 10.1016/j.cer.2007.06.001 %T Soluble dynamic coordination polymers as a paradigm for materials science %U http://dx.doi.org/10.1016/j.cer.2007.06.001 %V 252 %X Metal ion induced self-assembly of polytopic ligands can be employed to make macromolecular assemblies in solution. This new class of coordination polymers has recently attracted increasing interest. By carefully adjusting the boundary conditions of self-assembly it is possible to form soluble macromolecular assemblies in solution. For this, the binding constants between metal ions and ligands have to be of the appropriate strength. If the interaction is too weak, macromolecular species will not form, but if it is too strong, precipitation may occur. Intermediate binding constants imply a facile exchange of ligands, that is, soluble coordination polymers are generally dynamic equilibrium systems. Through the design of the ligands, the choice of the metal ions and through the pH, ionic strength, temperature and other experimental parameters it is possible to define a window of opportunity where soluble coordination polymers exist. However, the dynamic nature poses a great challenge for characterization because structure and property depend on the external conditions. Besides the value-adding properties of transition metal ions such as electrochemical, magnetic, optical and reactive parameters these polymers add a dynamic component to an already rich spectrum of polymer properties. The dynamic nature makes them unique for fundamental research to address questions concerning self-assembly thermodynamics and kinetics. Additionally, these polymers provide an enormous potential for the development of stimuli-responsive and intelligent materials. (C) 2007 Elsevier B.V. All rights reserved.

@article{Friese2008, abstract = {Metal ion induced self-assembly of polytopic ligands can be employed to make macromolecular assemblies in solution. This new class of coordination polymers has recently attracted increasing interest. By carefully adjusting the boundary conditions of self-assembly it is possible to form soluble macromolecular assemblies in solution. For this, the binding constants between metal ions and ligands have to be of the appropriate strength. If the interaction is too weak, macromolecular species will not form, but if it is too strong, precipitation may occur. Intermediate binding constants imply a facile exchange of ligands, that is, soluble coordination polymers are generally dynamic equilibrium systems. Through the design of the ligands, the choice of the metal ions and through the pH, ionic strength, temperature and other experimental parameters it is possible to define a window of opportunity where soluble coordination polymers exist. However, the dynamic nature poses a great challenge for characterization because structure and property depend on the external conditions. Besides the value-adding properties of transition metal ions such as electrochemical, magnetic, optical and reactive parameters these polymers add a dynamic component to an already rich spectrum of polymer properties. The dynamic nature makes them unique for fundamental research to address questions concerning self-assembly thermodynamics and kinetics. Additionally, these polymers provide an enormous potential for the development of stimuli-responsive and intelligent materials. (C) 2007 Elsevier B.V. All rights reserved.}, added-at = {2011-01-12T12:37:39.000+0100}, address = {PO BOX 564, 1001 LAUSANNE, SWITZERLAND}, affiliation = {Kurth, Dirk G. (Reprint Author), Max Planck Inst Colloids \& Interfaces, Muhlenberg 1, D-14476 Golm, Germany. {[}Friese, Viviane A.; Kurth, Dirk G.] Max Planck Inst Colloids \& Interfaces, D-14476 Golm, Germany. {[}Kurth, Dirk G.] Natl Inst Mat Sci, Organ Nanomat Ctr, Tsukuba, Ibaraki 3050044, Japan.}, author = {Friese, Viviane A. and Kurth, Dirk G.}, author-email = {kurth@mpikg.mpg.de}, biburl = {https://www.bibsonomy.org/bibtex/2dd4d1b40b30198d27675125a88252093/lctm}, cited-references = {BIDAULT S, 2006, ADV FUNCT MATER, V16, P2252, DOI 10.1002/adfm.200600157. BODENTHIN Y, 2005, J AM CHEM SOC, V127, P3110. BODENTHIN Y, 2005, J PHYS CHEM B, V109, P12795, DOI 10.1021/jp058001. BRUNSVELD L, 2000, MRS BULL, V25, P49. CASSOUX P, 1991, COORDIN CHEM REV, V110, P115. CERRADA E, 2001, SYNTHETIC MET, V119, P91. CHARLES E, 2005, MACROMOLECULES CONTA, P1. CHEN CT, 1993, COORDIN CHEM REV, V128, P293. COELFEN H, 1998, POLYM NEWS, V23, P152. COHENSTUART MA, 1998, LANGMUIR, V14, P6846. 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ZWEISTRA HJA, 2006, J PHYS CHEM B, V110, P18629, DOI 10.1021/jp064043z.}, doc-delivery-number = {253FG}, doi = {10.1016/j.cer.2007.06.001}, interhash = {88fb71bf88c8fd54e9360120ffa2c7cb}, intrahash = {dd4d1b40b30198d27675125a88252093}, issn = {0010-8545}, journal = {COORDINATION CHEMISTRY REVIEWS}, journal-iso = {Coord. Chem. Rev.}, keywords = {dgkurth}, keywords-plus = {METAL-ORGANIC FRAMEWORKS; NONLINEAR-OPTICAL PROPERTIES; SUPRAMOLECULAR POLYMERS; COLLOIDAL STABILITY; MAGNETIC-PROPERTIES; COMPLEXES; CHEMISTRY; POLYELECTROLYTES; TRANSITION; PERSPECTIVES}, language = {English}, month = jan, number = {1-2}, number-of-cited-references = {61}, pages = {199-211}, publisher = {ELSEVIER SCIENCE SA}, subject-category = {Chemistry, Inorganic \& Nuclear}, times-cited = {29}, timestamp = {2011-01-12T12:37:39.000+0100}, title = {Soluble dynamic coordination polymers as a paradigm for materials science}, type = {Review}, unique-id = {ISI:000252503500008}, url = {http://dx.doi.org/10.1016/j.cer.2007.06.001}, volume = 252, year = 2008 }