%0 Journal Article %1 Berndt:1998p3863 %A Berndt, T %A Kind, I %A Karbach, HJ %D 1998 %J Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics %K Alkenes, Atmospheric Chemical Chemistry, Coefficient, Constants Formation, Kinetics, Low-Pressures, No3 Organic-Compounds, Oxirane Radicals, Rate %N 10 %P 1486--1491 %T Kinetics of the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene using LIF detection %U http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reaction+of+NO3+radicals+with+1-butene,+trans-butene,+2-methyl-2-butene+and+2,3-dimethyl-2-butene+using+LIF+detection&ie=UTF-8&oe=UTF-8 %V 102 %X Rate constants for the gas-phase reaction of NO3 radicals with I-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298+/-2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M --> NO3+NO2+M.Applying pseudo-first-order conditions, the rate constants for I-butene and trans-butene were found to be (1.04+/-0.11). 10(-14) and (3.74+/-0.45). 10(-13), respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03+/-0.09). 10(-11) and (5.49+/-0.47). 10(-11), respectively (unit: cm(3) molecule(-1) s(-1)).

@article{Berndt:1998p3863, abstract = {Rate constants for the gas-phase reaction of NO3 radicals with I-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298+/-2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M --> NO3+NO2+M.Applying pseudo-first-order conditions, the rate constants for I-butene and trans-butene were found to be (1.04+/-0.11). 10(-14) and (3.74+/-0.45). 10(-13), respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03+/-0.09). 10(-11) and (5.49+/-0.47). 10(-11), respectively (unit: cm(3) molecule(-1) s(-1)).}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Inst Tropospharenforsch EV, D-04303 Leipzig, Germany}, author = {Berndt, T and Kind, I and Karbach, HJ}, biburl = {https://www.bibsonomy.org/bibtex/29176a07e0697a8cde8689eb558215bb9/gsmith}, date-added = {2010-05-18 10:07:06 -0400}, date-modified = {2010-05-18 10:07:13 -0400}, interhash = {8a35ef68fe5f3bc592ff8f9e42f7b355}, intrahash = {9176a07e0697a8cde8689eb558215bb9}, journal = {Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics}, keywords = {Alkenes, Atmospheric Chemical Chemistry, Coefficient, Constants Formation, Kinetics, Low-Pressures, No3 Organic-Compounds, Oxirane Radicals, Rate}, language = {English}, month = Jan, number = 10, pages = {1486--1491}, pmid = {000076550500015}, rating = {0}, timestamp = {2010-06-22T19:39:23.000+0200}, title = {Kinetics of the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene using LIF detection}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3863}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reaction+of+NO3+radicals+with+1-butene,+trans-butene,+2-methyl-2-butene+and+2,3-dimethyl-2-butene+using+LIF+detection&ie=UTF-8&oe=UTF-8}, volume = 102, year = 1998 }