%0 Journal Article %1 doi:10.1021/jp101964e %A Walter, Ch. %A Kritzer, R. %A Schubert, A. %A Meier, C. %A Dopfer, O. %A Engel, V. %D 2010 %J The Journal of Physical Chemistry A %K ak-engel %N 36 %P 9743-9748 %R 10.1021/jp101964e %T Dissipative Wave Packet Dynamics of Hydrophobic → Hydrophilic Site Switching in Phenol-Ar Clusters %U http://dx.doi.org/10.1021/jp101964e %V 114 %X We analyze the results of recent pump−probe experiments on the site-switching dynamics of Ar within cationic phenol-Ar2 clusters. A reaction-path model is employed for the wave packet dynamics. It is shown that the mechanism of energy dissipation is to be included to understand the features of the transient signals. Therefore, a simple recipe to include energy relaxation to the quantum dynamics is introduced. It is then possible to reproduce the measured pump−probe signals by adjustment of only two parameters.

@article{doi:10.1021/jp101964e, abstract = { We analyze the results of recent pump−probe experiments on the site-switching dynamics of Ar within cationic phenol-Ar2 clusters. A reaction-path model is employed for the wave packet dynamics. It is shown that the mechanism of energy dissipation is to be included to understand the features of the transient signals. Therefore, a simple recipe to include energy relaxation to the quantum dynamics is introduced. It is then possible to reproduce the measured pump−probe signals by adjustment of only two parameters. }, added-at = {2017-06-20T16:10:23.000+0200}, author = {Walter, Ch. and Kritzer, R. and Schubert, A. and Meier, C. and Dopfer, O. and Engel, V.}, biburl = {https://www.bibsonomy.org/bibtex/20906a4f262bfb9d40cba1b23a29d8919/ak-engel-uniwue}, description = {Dissipative Wave Packet Dynamics of Hydrophobic → Hydrophilic Site Switching in Phenol-Ar Clusters - The Journal of Physical Chemistry A (ACS Publications)}, doi = {10.1021/jp101964e}, eprint = {http://dx.doi.org/10.1021/jp101964e}, interhash = {8a684b0f1da596c9ce4222e6aac2e80b}, intrahash = {0906a4f262bfb9d40cba1b23a29d8919}, journal = {The Journal of Physical Chemistry A}, keywords = {ak-engel}, note = {PMID: 20433178}, number = 36, pages = {9743-9748}, timestamp = {2017-06-20T16:10:23.000+0200}, title = {Dissipative Wave Packet Dynamics of Hydrophobic → Hydrophilic Site Switching in Phenol-Ar Clusters}, url = {http://dx.doi.org/10.1021/jp101964e}, volume = 114, year = 2010 }