Abstract
We consider a model colloidal dispersion of hard platelets with
circular shapes, vanishing thickness and continuous position and
orientation degrees of freedom. Using density functional theory we
investigate the wetting behaviour of the nematic phase at a hard
wall upon approaching bulk isotropic-nematic coexistence, the
influence of an external magnetic field on the bulk isotropic-nematic
phase transition and capillary phase transitions of the system when
confined between parallel hard walls. We find that a single wall is
wet completely by the nematic phase, that isotropic-nematic
coexistence vanishes above a critical field strength and that two
parallel walls induce capillary nematization. Some of our findings
are compared to literature results from extensive Monte Carlo
simulations and from experiments with dispersions of sterically
stabilized Gibbsite platelets adsorbed against a glass wall.
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