Article,

Platinum(VI) dihydroxo tetramesitylporphyrin; characterization and chemical reactivity

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INORGANIC CHEMISTRY COMMUNICATIONS, 11 (12): 1459-1461 (December 2008)
DOI: {10.1016/j.inoche.2008.09.022}

Abstract

Tetramesitylporphyrin platinum(VI) dihydroxo complex, TMPPt(OH)(2) center dot 2 benzoate was synthesized by addition of two equivalent of meta-chloroperbenzoic acid molecules to the tetramesitylporphyrin platinum(II). This complex was characterized by X-ray diffraction and spectroscopic methods, and is capable to convert two molecules of triphenylphosphine to triphenylphosphine oxide. (c) 2008 Published by Elsevier B.V.

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