%0 Journal Article %1 schlecht2011functionalization %A Schlecht, Clifford A. %A Maurer, Joshua A. %D 2011 %I The Royal Society of Chemistry %J RSC Adv. %K fabrication phd %N 8 %P 1446--1448 %R 10.1039/C1RA00421B %T Functionalization of glass substrates: mechanistic insights into the surface reaction of trialkoxysilanes %U http://dx.doi.org/10.1039/C1RA00421B %V 1 %X Modification of substrates by trialkoxysilane reagents is the most common method employed for surface functionalization. Classically, the mechanism for surface reactivity in trialkoxysilanes is described as proceeding through a trisilanol intermediate. Here, we present data that contradict this mechanism and propose an alternative mechanism, in which trialkoxysilanes react directly with surface hydroxyl groupsvia an addition-elimination type mechanism.

@article{schlecht2011functionalization, abstract = {Modification of substrates by trialkoxysilane reagents is the most common method employed for surface functionalization. Classically{,} the mechanism for surface reactivity in trialkoxysilanes is described as proceeding through a trisilanol intermediate. Here{,} we present data that contradict this mechanism and propose an alternative mechanism{,} in which trialkoxysilanes react directly with surface hydroxyl groupsvia an addition-elimination type mechanism.}, added-at = {2014-08-07T12:49:58.000+0200}, author = {Schlecht, Clifford A. and Maurer, Joshua A.}, biburl = {https://www.bibsonomy.org/bibtex/2392f0ce4ae32bde1d2d8550d1f5a5959/bkoch}, description = {Functionalization of glass substrates: mechanistic insights into the surface reaction of trialkoxysilanes - RSC Advances (RSC Publishing)}, doi = {10.1039/C1RA00421B}, interhash = {bbb62a405f2a1626c23123f38e107af5}, intrahash = {392f0ce4ae32bde1d2d8550d1f5a5959}, journal = {RSC Adv.}, keywords = {fabrication phd}, number = 8, pages = {1446--1448}, publisher = {The Royal Society of Chemistry}, timestamp = {2014-08-07T12:49:58.000+0200}, title = {Functionalization of glass substrates: mechanistic insights into the surface reaction of trialkoxysilanes}, url = {http://dx.doi.org/10.1039/C1RA00421B}, volume = 1, year = 2011 }