Article,

Photovoltaic and photo-capacitance effects in ferroelectric BiFeO3 thin film

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Applied Physics Letters, 110 (19): 192906 (2017)

Abstract

A polycrystalline BiFeO3 film on Pt/Ti/SiO2/Si was fabricated using the spin coating technique. The film shows diode-like characteristics with and without poling measured under dark conditions. However, it exhibits a switchable photovoltaic effect with light illumination under poled condi- tions. The measured photovoltaic effect revealed an open circuit voltage of $0.47 V and a short cir- cuit current of 3.82 lA/cm 2 under the illumination of 165 mW/cm 2 irradiance. The studies clarified the dominant role of the depolarization field rather than the interface in the photovoltaic character- istics of the BiFeO 3 film. Significantly, the photo-capacitance effect was demonstrated with a sub- stantial enhancement in capacitance ($45%) in Au/BiFeO3 /Pt geometry, which could open up a new window for BiFeO 3 applications.

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