%0 Journal Article %1 Glasius:1997p2686 %A Glasius, M %A Calogirou, A %A Jensen, NR %A Hjorth, J %A Nielsen, CJ %D 1997 %J International Journal of Chemical Kinetics %K Air, Alpha-Pinene, Beta-Pinene, Co, Constants, Oh, Organic-Compounds Oxidation, Products, Radicals, Rate %N 7 %P 527--533 %T Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds %U http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+study+of+gas-phase+reactions+of+pinonaldehyde+and+structurally+related+compounds&ie=UTF-8&oe=UTF-8 %V 29 %X Rate constants for the reactions of OH, NO3, and O-3 with pinonaldehyde and the structurally related compounds 3-methylbutanal, 3-methylbutan-2-one, cyclobutyl-methylketone, and 2,2,3-trimethyl-cyclobutyl-1-ethanone have been measured at 300 +/- 5 K using on-line Fourier transform infrared spectroscopy. The rate constants obtained for the reactions with pinonaldehyde were: k(OH)=(9.1 +/- 1.8) x 10(-11) cm(3) molecule(-1) s(-1), k(NO3) = (5.4 +/- 1.8) x 10(-14) cm(3) molecule(-1) s(-1), and k(O3) = (8.9 +/- 1.4) x 10(-20) cm(3) molecule(-1) s(-1). The results obtained indicate a chemical lifetime of pinonaldehyde in the troposphere of about two hours under typical daytime conditions, OH = 1.6 x 10(6) molecule cm(-3). (C) 1997 John Wiley and Sons, Inc.

@article{Glasius:1997p2686, abstract = {Rate constants for the reactions of OH, NO3, and O-3 with pinonaldehyde and the structurally related compounds 3-methylbutanal, 3-methylbutan-2-one, cyclobutyl-methylketone, and 2,2,3-trimethyl-cyclobutyl-1-ethanone have been measured at 300 +/- 5 K using on-line Fourier transform infrared spectroscopy. The rate constants obtained for the reactions with pinonaldehyde were: k(OH)=(9.1 +/- 1.8) x 10(-11) cm(3) molecule(-1) s(-1), k(NO3) = (5.4 +/- 1.8) x 10(-14) cm(3) molecule(-1) s(-1), and k(O3) = (8.9 +/- 1.4) x 10(-20) cm(3) molecule(-1) s(-1). The results obtained indicate a chemical lifetime of pinonaldehyde in the troposphere of about two hours under typical daytime conditions, [OH] = 1.6 x 10(6) molecule cm(-3). (C) 1997 John Wiley and Sons, Inc.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {COMMISS EUROPEAN COMMUNITIES,JOINT RES CTR,INST ENVIRONM,I-21020 ISPRA,VA,ITALY}, author = {Glasius, M and Calogirou, A and Jensen, NR and Hjorth, J and Nielsen, CJ}, biburl = {https://www.bibsonomy.org/bibtex/22bd30ccd505e2bda3684ebb0e5e5383e/gsmith}, date-added = {2010-03-31 12:06:52 -0400}, date-modified = {2010-03-31 12:06:59 -0400}, interhash = {ca781f09c8e6b96d3d66fbef17ffab2c}, intrahash = {2bd30ccd505e2bda3684ebb0e5e5383e}, journal = {International Journal of Chemical Kinetics}, keywords = {Air, Alpha-Pinene, Beta-Pinene, Co, Constants, Oh, Organic-Compounds Oxidation, Products, Radicals, Rate}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/International%20Journal%20of%20Chemical%20Kinetics/1997/International%20Journal%20of%20Chemical%20Kinetics,%2029,%20527-533%201997.pdf}, month = Jan, number = 7, pages = {527--533}, pmid = {A1997XF92400007}, rating = {0}, read = {Yes}, timestamp = {2010-06-22T19:39:33.000+0200}, title = {Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p2686}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+study+of+gas-phase+reactions+of+pinonaldehyde+and+structurally+related+compounds&ie=UTF-8&oe=UTF-8}, volume = 29, year = 1997 }