%0 Journal Article %1 Kozitsyna2011382 %A Kozitsyna, Natalia Yu. %A Nefedov, Sergei E. %A Klyagina, Alla P. %A Markov, Alexander A. %A Dobrokhotova, Zhanna V. %A Velikodny, Yuri A. %A Kochubey, Dmitry I. %A Zyubina, Tatiana S. %A Gekhman, Alexander E. %A Vargaftik, Michael N. %A Moiseev, Ilya I. %D 2011 %J Inorganica Chimica Acta %K myown %N 1 %P 382 - 387 %R http://dx.doi.org/10.1016/j.ica.2011.02.003 %T Novel heterometallic palladium–silver complex %U http://www.sciencedirect.com/science/article/pii/S0020169311001484 %V 370 %X The reaction between Pd3(OOCMe)6 and Ag2(OOCMe)2 afforded the first palladium–silver heterometallic acetate-bridged complex PdII(μ-OOCMe)2AgI(HOOCMe)22 (1). The molecular geometry and electronic structure of 1 were studied by single-crystal \XRD\ and quantum-chemical \DFT\ calculations. Thermal transformations of 1 in vacuo and under Ar, \H2\ produced PdAg alloy nanoparticles characterized with powder \XRD\ and EXAFS.

@article{Kozitsyna2011382, abstract = {The reaction between Pd3(OOCMe)6 and Ag2(OOCMe)2 afforded the first palladium–silver heterometallic acetate-bridged complex PdII[(μ-OOCMe)2AgI(HOOCMe)2]2 (1). The molecular geometry and electronic structure of 1 were studied by single-crystal \{XRD\} and quantum-chemical \{DFT\} calculations. Thermal transformations of 1 in vacuo and under Ar, \{H2\} produced PdAg alloy nanoparticles characterized with powder \{XRD\} and EXAFS. }, added-at = {2015-05-13T15:39:53.000+0200}, author = {Kozitsyna, Natalia Yu. and Nefedov, Sergei E. and Klyagina, Alla P. and Markov, Alexander A. and Dobrokhotova, Zhanna V. and Velikodny, Yuri A. and Kochubey, Dmitry I. and Zyubina, Tatiana S. and Gekhman, Alexander E. and Vargaftik, Michael N. and Moiseev, Ilya I.}, biburl = {https://www.bibsonomy.org/bibtex/2bab1c3ee00420e3464366a641a7bac33/gekhman}, doi = {http://dx.doi.org/10.1016/j.ica.2011.02.003}, interhash = {e12033aa20abf9f95255ee03aa7ca519}, intrahash = {bab1c3ee00420e3464366a641a7bac33}, issn = {0020-1693}, journal = {Inorganica Chimica Acta }, keywords = {myown}, number = 1, pages = {382 - 387}, timestamp = {2015-05-13T15:39:53.000+0200}, title = {Novel heterometallic palladium–silver complex }, url = {http://www.sciencedirect.com/science/article/pii/S0020169311001484}, volume = 370, year = 2011 }