%0 Journal Article %1 ISI:000265993300006 %A Amani, Vahid %A Safari, Nasser %A Notash, Behrouz %A Khavasi, Hamid Reza %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2009 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K 2'-bipyridine; 4'-Dimethyl-2; 4; Chloride; Crystal Dimethyl structure} sulfoxide; {Iron(III); %N 12 %P 1939-1950 %R 10.1080/00958970902736764 %T Synthesis, characterization and crystal structure determination of iron(III) complexes containing 4,4'-dimethyl-2,2'-bipyridine, dimethyl sulfoxide and chloride, Fe(dmbipy)Cl4dmbipyH and Fe(dmbipy)Cl3(DMSO) %V 62 %X Fe(dmbipy)Cl4dmbipyH, 1 (dmbipy is 4,4'-dimethyl-2,2'-bipyridine), was prepared from reaction of FeCl3 6H2O with 4,4'-dimethyl-2,2'-bipyridine in 0.1 molar aqueous HCl. Treatment of 1 with dimethyl sulfoxide in methanol produced Fe(dmbipy)Cl3(DMSO), 2 (DMSO is dimethyl sulfoxide). Both complexes were characterized by IR, UV-vis, and 1H-NMR spectroscopies and their structures were studied by single crystal diffraction. Compounds 1 and 2 are high-spin with spin multiplicity of six.

@article{ISI:000265993300006, abstract = {{{[}Fe(dmbipy)Cl4]{[}dmbipyH], 1 (dmbipy is 4,4'-dimethyl-2,2'-bipyridine), was prepared from reaction of FeCl3 6H2O with 4,4'-dimethyl-2,2'-bipyridine in 0.1 molar aqueous HCl. Treatment of 1 with dimethyl sulfoxide in methanol produced {[}Fe(dmbipy)Cl3(DMSO)], 2 (DMSO is dimethyl sulfoxide). Both complexes were characterized by IR, UV-vis, and 1H-NMR spectroscopies and their structures were studied by single crystal diffraction. Compounds 1 and 2 are high-spin with spin multiplicity of six.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shaheed Beheshti Univ, Dept Chem, Tehran, Iran. Amani, Vahid; Safari, Nasser; Notash, Behrouz; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran, Iran.}}, article-number = {{PII 909098348}}, author = {Amani, Vahid and Safari, Nasser and Notash, Behrouz and Khavasi, Hamid Reza}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/28bc7df46587790c975452e147e1f3a1c/hkhavasi}, cited-references = {{Amani V, 2007, POLYHEDRON, V26, P4908, DOI 10.1016/j.poly.2007.06.038. Amani V, 2007, POLYHEDRON, V26, P4257, DOI 10.1016/j.poly.2007.05.050. ANDEREGG G, 1962, HELV CHIM ACTA, V45, P1643, DOI 10.1002/hlca.19620450532. Batten SR, 2000, ACTA CRYSTALLOGR C, V56, pE320, DOI 10.1107/S0108270100009185. BERRETT RR, 1968, J CHEM SOC A, P1575, DOI 10.1039/j19680001575. Collomb MN, 1999, NEW J CHEM, V23, P785, DOI 10.1039/a901893j. EARNSHAW A, 1961, J CHEM SOC, P396, DOI 10.1039/jr9610000396. EVANS DF, 1959, J CHEM SOC, P2003, DOI 10.1039/jr9590002003. FIGGIS BN, 1983, AUST J CHEM, V36, P2043. FIGGIS BN, 1964, PROG INORG CHEM, V6, P168. Fu XC, 2005, ACTA CRYSTALLOGR E, V61, pM1221, DOI 10.1107/S1600536805016156. Gaines A, 1936, J AM CHEM SOC, V58, P1668, DOI 10.1021/ja01300a050. GHOSH SN, 1975, INDIAN J CHEM, V13, P66. GOODWIN HJ, 1977, INORG CHIM ACTA, V25, pL74, DOI 10.1016/S0020-1693(00)95651-2. HARRIS CM, 1958, CHEM IND-LONDON, P1231. HEALY PC, 1983, AUST J CHEM, V36, P2031. HEALY PC, 1983, AUST J CHEM, V36, P2057. Huang W, 2006, TRANSIT METAL CHEM, V31, P621, DOI 10.1007/s11243-006-0039-8. Huang W, 2006, J MOL STRUCT, V785, P21, DOI 10.1016/j.molstruc.2005.09.035. IRVING H, 1949, J CHEM SOC, P1489, DOI 10.1039/jr9490001489. Khavasi HR, 2008, Z KRIST-NEW CRYST ST, V223, P41, DOI 10.1524/ncrs.2008.0020. Khavasi HR, 2007, Z KRIST-NEW CRYST ST, V222, P155, DOI 10.1524/ncrs.2007.0063. KHEDEKAR AV, 1967, J CHEM SOC A, P1561, DOI 10.1039/j19670001561. Kulkarni P, 1998, POLYHEDRON, V17, P2623, DOI 10.1016/S0277-5387(97)00515-9. Michaelis L, 1943, J AM CHEM SOC, V65, P481, DOI 10.1021/ja01243a507. NAKAGAWA Y, 1997, DENSHI KENBIKYO, V32, P5. Odoko M, 2004, ACTA CRYSTALLOGR E, V60, pM1822, DOI 10.1107/S1600536804027345. Plaza LA, 2007, ACTA CRYSTALLOGR E, V63, pM1537, DOI 10.1107/S1600536807019873. Poulsen RD, 2001, ACTA CRYSTALLOGR E, V57, pM186, DOI 10.1107/S1600536801005918. Reipff W. M., 1975, INORG CHEM, V14, P800. SAITO Y, 1972, INORG CHEM, V11, P2003, DOI 10.1021/ic50115a004. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. SIMON A, 1937, ANORG ALLG CHEM, V230, P225. {[}Anonymous], 2004, X SHAPE VERS 2 05 PR. {*}STOE CIE GMBH, 2005, X RED VES 1 28B PROG. Stoe\&Cie, 2000, X STEP32 VERS 1 07B. Stoe \& Cie, 2005, X AREA VES 1 30 PROG. WITTEN EH, 1985, INORG CHEM, V24, P4585, DOI 10.1021/ic00220a031. 1995, INT TABLES XRAY CYST, VC.}}, doc-delivery-number = {{444PQ}}, doi = {{10.1080/00958970902736764}}, funding-acknowledgement = {{Iranian National Science Foundation; Research and Graduate Study Councils of Shahid Beheshti University}}, funding-text = {{We would like to thank the Iranian National Science Foundation and Research and Graduate Study Councils of Shahid Beheshti University for financial support.}}, interhash = {f3477cc7c12204480a51daa489d0def8}, intrahash = {8bc7df46587790c975452e147e1f3a1c}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {2'-bipyridine; 4'-Dimethyl-2; 4; Chloride; Crystal Dimethyl structure} sulfoxide; {Iron(III);}, keywords-plus = {{ALPHA,ALPHA'-DIIMINE SYSTEM; MAGNETIC-SUSCEPTIBILITY; HETEROLIGAND COMPLEXES; 1,10-PHENANTHROLINE; 2,2'-BIPYRIDINE; DERIVATIVES; MONONUCLEAR; REFINEMENT; IRON(3); SOLVATE}}, language = {{English}}, number = {{12}}, number-of-cited-references = {{39}}, pages = {{1939-1950}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{22}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization and crystal structure determination of iron(III) complexes containing 4,4'-dimethyl-2,2'-bipyridine, dimethyl sulfoxide and chloride, {[}Fe(dmbipy)Cl4]{[}dmbipyH] and {[}Fe(dmbipy)Cl3(DMSO)]}}, type = {{Article}}, unique-id = {{ISI:000265993300006}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{5}}, volume = {{62}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2009}} }