Article,

Optical 2nd-Harmonic Susceptibilities - Frequency-Dependent Formulation With Results For Gap And Gaas

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Physical Review B, 49 (7): 4532--4538 (February 1994)

Abstract

A formula for frequency-dependent optical second-harmonic susceptibilities for insulating crystals, including local-field corrections, is presented. In analogy to a formula given previously for the static limit, the formula is analyzed in terms of ''virtual electron'' (ccv) and ''virtual hole'' (vvc) terms to obtain a numerically stable form. Numerical results for GaP and GaAs agree with most of the experimental values suggested in a recent review article by Roberts. Miller's DELTA(M) is predicted to vary by 13% from the laser lines at 10.6 to 1.32 mum for GaP.

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