%0 Journal Article %1 ISI:000249905900029 %A Amani, Vahid %A Safari, Nasser %A Khavasi, Hamid Reza %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2007 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K 2,2 5,5 `-Bipyridine; `-Dimethyl-2,2 `-bipyridine; crystal structure} {iron(III); %N 15 %P 4257-4262 %R 10.1016/j.poly.2007.05.050 %T Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2 `-bipyridine, 5,5 `-dimethyl-2,2 `-bipyridine and chloride, Fe(bipy)Cl-4bipy center dot H and Fe(dmbipy)(2)Cl-2FeCl4 %V 26 %X The complex Fc(bipy)Cl4bipy-H (1) (bipy is 2,2'-bipyridine) was prepared from the reaction of FeCl3 center dot 6H(2)O with 2,2'-bipyridine in a 0.1 M aqueous solution of HCl. The same method was employed to make Fe(dmbipy)(2)Cl-2FeCl4(2) (dmbipy is 5,5'-dimethyl-2,2'bipyridine). Both complexes were characterized by IR, UV-Vis and H-1 NMR spectroscopies and single-crystal X-ray diffraction. These complexes are HS with a spin multiplicity of 6. Crystal data for I at 20 degrees C: orthorhombic, space group Pna2(1), a = 15.938(2) angstrom. b = 9.3068(15) angstrom, c = 14.513(3) angstrom, Z = 4, R, = 0.0406 and for 2 at 20 degrees C: triclinic, space group P \$(1) over bar \$, a = 8.6072(13) angstrom, b = 18.008(3) angstrom, c = 20.311(3) angstrom, alpha = 103.652(13)degrees,beta = 95.421(12)degrees, gamma = 98.724(13)degrees, Z = 4, R-1 = 0.0634. (c) 2007 Elsevier Ltd. All rights reserved.

@article{ISI:000249905900029, abstract = {{The complex {[}Fc(bipy)Cl4]{[}bipy-H] (1) (bipy is 2,2'-bipyridine) was prepared from the reaction of FeCl3 center dot 6H(2)O with 2,2'-bipyridine in a 0.1 M aqueous solution of HCl. The same method was employed to make {[}Fe(dmbipy)(2)Cl-2]{[}FeCl4](2) (dmbipy is 5,5'-dimethyl-2,2'bipyridine). Both complexes were characterized by IR, UV-Vis and H-1 NMR spectroscopies and single-crystal X-ray diffraction. These complexes are HS with a spin multiplicity of 6. Crystal data for I at 20 degrees C: orthorhombic, space group Pna2(1), a = 15.938(2) angstrom. b = 9.3068(15) angstrom, c = 14.513(3) angstrom, Z = 4, R, = 0.0406 and for 2 at 20 degrees C: triclinic, space group P \$(1) over bar \$, a = 8.6072(13) angstrom, b = 18.008(3) angstrom, c = 20.311(3) angstrom, alpha = 103.652(13)degrees,beta = 95.421(12)degrees, gamma = 98.724(13)degrees, Z = 4, R-1 = 0.0634. (c) 2007 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Amani, Vahid and Safari, Nasser and Khavasi, Hamid Reza}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/233303e83189169ee156c17df35b7621d/hkhavasi}, cited-references = {{BAKIR M, 1992, INORG CHEM, V31, P1129. BARTON JK, 1989, PURE APPL CHEM, V61, P563, DOI 10.1351/pac198961030563. CLAUDE R, 1990, INORG CHEM, V29, P4442, DOI 10.1021/ic00347a022. CONSTABLE EC, 1989, COORDIN CHEM REV, V93, P205. CORDES AW, 1982, J COORD CHEM, V11, P251, DOI 10.1080/00958978208079745. DENTI G, 1990, INORG CHEM, V29, P4750, DOI 10.1021/ic00348a032. FIGGIS BN, 1983, ACTA CRYSTALLOGR B, V39, P711, DOI 10.1107/S0108768183003286. GUTLICH P, 1994, ANGEW CHEM INT EDIT, V33, P2024, DOI 10.1002/anie.199420241. Hawker P.N., 1987, COMPREHENSIVE COORDI, V4. Hazell A, 2004, POLYHEDRON, V23, P2081, DOI 10.1016/j.poly.2004.06.001. HUTCHINSON B, 1970, J AM CHEM SOC, V3, P335. KALYANASUNDARAM K, 1982, COORDIN CHEM REV, V46, P159, DOI 10.1016/0010-8545(82)85003-0. Kasselouri S, 1998, POLYHEDRON, V17, P1281, DOI 10.1016/S0277-5387(97)00375-6. Kopel P, 2004, POLYHEDRON, V23, P2193, DOI 10.1016/j.poly.2004.06.024. Kulkarni P, 1998, POLYHEDRON, V17, P2623, DOI 10.1016/S0277-5387(97)00515-9. Lescouezec R, 2002, INORG CHEM, V41, P818, DOI 10.1021/ic0107882. LU TH, 1988, ACTA CRYSTALLOGR C, V44, P1184, DOI 10.1107/S0108270188003828. Nieuwenhuyzen M, 1998, ACTA CRYSTALLOGR C, V54, P603, DOI 10.1107/S0108270197018039. Pouchert C. J., 1981, ALDRICH LIB INFRARED. Poulsen RD, 2001, ACTA CRYSTALLOGR E, V57, pM186, DOI 10.1107/S1600536801005918. Reipff W. M., 1975, INORG CHEM, V14, P800. SAITO Y, 1972, INORG CHEM, V11, P2003, DOI 10.1021/ic50115a004. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. STEEL PJ, 1990, COORDIN CHEM REV, V106, P227, DOI 10.1016/0010-8545(60)80005-7. Stoe C., 2005, XAREA VERSION 1 30 P. Stoe C., 2000, XSTEP32 VERSION 1 07. STOE C, 2005, XRED VERSION 1 28 PR. TAKEMOTO JH, 1973, INORG CHEM, V12, P705, DOI 10.1021/ic50121a049.}}, doc-delivery-number = {{216VA}}, doi = {{10.1016/j.poly.2007.05.050}}, interhash = {500b070be17715b8f53ff05186df466d}, intrahash = {33303e83189169ee156c17df35b7621d}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {2,2 5,5 `-Bipyridine; `-Dimethyl-2,2 `-bipyridine; crystal structure} {iron(III);}, keywords-plus = {{METAL-COMPLEXES; 1,10-PHENANTHROLINE; MOSSBAUER; DINUCLEAR; LIGANDS; DESIGN}}, language = {{English}}, month = {{SEP 20}}, number = {{15}}, number-of-cited-references = {{28}}, pages = {{4257-4262}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{44}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2 `-bipyridine, 5,5 `-dimethyl-2,2 `-bipyridine and chloride, {[}Fe(bipy)Cl-4]{[}bipy center dot H] and {[}Fe(dmbipy)(2)Cl-2]{[}FeCl4]}}, type = {{Article}}, unique-id = {{ISI:000249905900029}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{7}}, volume = {{26}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2007}} }