%0 Journal Article %1 ISI:000260309900001 %A Notash, Behrouz %A Safari, Nasser %A Khavasi, Hamid Reza %A Amani, Vahid %A Abedi, Anita %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2008 %I ELSEVIER SCIENCE SA %J JOURNAL OF ORGANOMETALLIC CHEMISTRY %K 2,2 C-H Crystal Transoid `-Dimethyl-4,4 `-bithiazole; activation; conformation; structure} {Thallium; %N 24 %P 3553-3557 %R 10.1016/j.jorganchem.2008.08.027 %T C-H activation in bithiazole ring with thallium(III) ion %V 693 %X Two novel organometallic complex of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) ligand (L) with formula TI(dm4bt)(2)(NO(3))(H(2)O) (1) and TI(dm4bt)(2)(NO(3))(DMSO) (2) have been synthesized and structurally characterized by elemental analysis, FT-IR, (1)H NMR spectra and X-ray crystallography. These complexes also display the first transoid conformation in bithiazole ligands in which C-H bond activation in bithiazole ring is observed with TI(III) ion. (C) 2008 Published by Elsevier B. V.

@article{ISI:000260309900001, abstract = {{Two novel organometallic complex of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) ligand (L) with formula {[}TI(dm4bt)(2)(NO(3))(H(2)O)] (1) and {[}TI(dm4bt)(2)(NO(3))(DMSO)] (2) have been synthesized and structurally characterized by elemental analysis, FT-IR, (1)H NMR spectra and X-ray crystallography. These complexes also display the first transoid conformation in bithiazole ligands in which C-H bond activation in bithiazole ring is observed with TI(III) ion. (C) 2008 Published by Elsevier B. V.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{PO BOX 564, 1001 LAUSANNE, SWITZERLAND}}, affiliation = {{Safari, N (Reprint Author), Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Notash, Behrouz; Safari, Nasser; Khavasi, Hamid Reza; Amani, Vahid; Abedi, Anita, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Notash, Behrouz and Safari, Nasser and Khavasi, Hamid Reza and Amani, Vahid and Abedi, Anita}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/247b5190b737f2a6098d297c34d659830/hkhavasi}, cited-references = {{Amani V, 2007, POLYHEDRON, V26, P4257, DOI 10.1016/j.poly.2007.05.050. Ara I, 2004, CHEM-EUR J, V10, P4186, DOI 10.1002/chem.200400141. {*}CCDC, CAMBR STRUCT DAT BAS. DREW MGB, 1983, POLYHEDRON, V2, P269, DOI 10.1016/S0277-5387(00)83912-1. Gornitzka H, 1998, EUR J INORG CHEM, P311. Khavasi HR, 2008, POLYHEDRON, V27, P1848, DOI 10.1016/j.poly.2008.02.029. Liu L, 2006, J ORGANOMET CHEM, V691, P1092, DOI 10.1016/j.jorganchem.2005.11.014. Lobana TS, 2003, INORG CHIM ACTA, V347, P23, DOI 10.1016/S0020-1693(03)01433-0. Ma GB, 2003, INORG CHIM ACTA, V344, P117, DOI 10.1016/S0020-1693(02)01315-4. Mendia A, 2002, J ORGANOMET CHEM, V663, P289, DOI 10.1016/S0022-328X(02)01961-7. Nakamato K., 1997, INFRARED RAMAN SPE B. NOTASH B, J COORD CHE IN PRESS. Prince E, 2004, INT TABLES XRAY CRYS, VC. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. Stoe Cie, 2005, X RED VERS 1 28B PRO. Stoe \& Cie, 2004, X SHAPE VERS 2 05 PR. Stoe \& Cie, 2005, X AREA VERS 1 30 PRO. Stoe \& Cie, 2000, X STEP32 VERS 1 07B. VICENTE J, 1989, J CHEM SOC DALTON, P2241, DOI 10.1039/dt9890002241. Wong WY, 2002, ORGANOMETALLICS, V21, P4475, DOI 10.1021/om020517e. Wong WY, 2000, MACROMOL RAPID COMM, V21, P453, DOI 10.1002/(SICI)1521-3927(20000501)21:8<453::AID-MARC453>3.0.CO;2-7. Zucca A, 2004, EUR J INORG CHEM, P4484, DOI 10.1002/ejic.200400371.}}, doc-delivery-number = {{364AZ}}, doi = {{10.1016/j.jorganchem.2008.08.027}}, funding-acknowledgement = {{Graduate Study Councils of Shahid Beheshti University}}, funding-text = {{We would like to thank Graduate Study Councils of Shahid Beheshti University for financial support.}}, interhash = {454b74ba5335e83194244477fe200be6}, intrahash = {47b5190b737f2a6098d297c34d659830}, issn = {{0022-328X}}, journal = {{JOURNAL OF ORGANOMETALLIC CHEMISTRY}}, journal-iso = {{J. Organomet. Chem.}}, keywords = {2,2 C-H Crystal Transoid `-Dimethyl-4,4 `-bithiazole; activation; conformation; structure} {Thallium;}, keywords-plus = {{CRYSTAL-STRUCTURE DETERMINATION; MERCURY(II) COMPLEXES; SOLID-STATE; COORDINATION; DERIVATIVES}}, language = {{English}}, month = {{NOV 15}}, number = {{24}}, number-of-cited-references = {{22}}, orcid-numbers = {{, Anita/0000-0001-7562-6241}}, pages = {{3553-3557}}, publisher = {{ELSEVIER SCIENCE SA}}, research-areas = {{Chemistry}}, times-cited = {{20}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{C-H activation in bithiazole ring with thallium(III) ion}}, type = {{Article}}, unique-id = {{ISI:000260309900001}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{4}}, volume = {{693}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Chemistry, Organic}}, year = {{2008}} }