Аннотация
Two novel organometallic complex of 2,2'-dimethyl-4,4'-bithiazole
(dm4bt) ligand (L) with formula TI(dm4bt)(2)(NO(3))(H(2)O) (1) and
TI(dm4bt)(2)(NO(3))(DMSO) (2) have been synthesized and structurally
characterized by elemental analysis, FT-IR, (1)H NMR spectra and X-ray
crystallography. These complexes also display the first transoid
conformation in bithiazole ligands in which C-H bond activation in
bithiazole ring is observed with TI(III) ion. (C) 2008 Published by
Elsevier B. V.
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