%0 Journal Article %1 ISI:000272979900002 %A Rahimi, Rahmatollah %A Tehrani, Alireza Azhdari %A Fard, Mahmood Azizpoor %A Sadegh, Bahareh Mir Mohammad %A Khavasi, Hamid Reza %C PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS %D 2009 %I ELSEVIER SCIENCE BV %J CATALYSIS COMMUNICATIONS %K Hydrogen Sulfoxidation; Tetraphenyl-2,3-dihydroxy-2,3-chlorin complex; metal peroxide} {Tetraphenylporpholactone %N 4 %P 232-235 %R 10.1016/j.catcom.2009.09.022 %T First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction %V 11 %X Iron and manganese complexes meso-tetraphenylporpholactone, MTPPLX, and meso-tetraphenyl-2,3-dihydroxy-2,3-chiorin, MTPP(OH)(2)X (X = Cl and (CH(3)COO)), are efficient catalysts for selective oxidation of sulfides with hydrogen peroxide. The effect of catalyst concentration on the conversion, selectivity and yield of products were studied. The results show that iron and manganese porpholactones and chlorins are a slightly better catalyst than TPP analogues for most sulfide substrates. (C) 2009 Elsevier B.V. All rights reserved.

@article{ISI:000272979900002, abstract = {{Iron and manganese complexes meso-tetraphenylporpholactone, MTPPLX, and meso-tetraphenyl-2,3-dihydroxy-2,3-chiorin, MTPP(OH)(2)X (X = Cl and (CH(3)COO)), are efficient catalysts for selective oxidation of sulfides with hydrogen peroxide. The effect of catalyst concentration on the conversion, selectivity and yield of products were studied. The results show that iron and manganese porpholactones and chlorins are a slightly better catalyst than TPP analogues for most sulfide substrates. (C) 2009 Elsevier B.V. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS}}, affiliation = {{Khavasi, HR (Reprint Author), Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Fard, Mahmood Azizpoor; Sadegh, Bahareh Mir Mohammad; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Rahimi, Rahmatollah; Tehrani, Alireza Azhdari, Iran Univ Sci \& Technol, Coll Chem, Tehran 1664613114, Iran.}}, author = {Rahimi, Rahmatollah and Tehrani, Alireza Azhdari and Fard, Mahmood Azizpoor and Sadegh, Bahareh Mir Mohammad and Khavasi, Hamid Reza}, author-email = {{h-khavasi@sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/214fa7227c25d7fe9da003fe5dc32b9bf/hkhavasi}, cited-references = {{ADLER AD, 1970, J INORG NUCL CHEM, V32, P2443, DOI 10.1016/0022-1902(70)80535-8. ADLER AD, 1967, J ORG CHEM, V32, P476, DOI 10.1021/jo01288a053. Li W., 1998, TETRAHEDRON LETT, V39, P7075. Bruckner C, 1998, J ORG CHEM, V63, P2094, DOI 10.1021/jo971156t. Campestrini S, 2000, J MOL CATAL A-CHEM, V164, P263, DOI 10.1016/S1381-1169(00)00353-8. Campos-Martin JM, 2004, GREEN CHEM, V6, P557, DOI 10.1039/b409882j. Carreno MC, 2002, ANGEW CHEM INT EDIT, V41, P2753, DOI 10.1002/1521-3773(20020802)41:15<2753::AID-ANIE2753>3.0.CO;2-M. CETIN A, 2005, J CHEM SOC DA, P25. 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Zhou Q.L., 1991, J MOL CATAL, V64, P19.}}, doc-delivery-number = {{535OK}}, doi = {{10.1016/j.catcom.2009.09.022}}, funding-acknowledgement = {{Iran University of Science and Technology; Shahid Beheshti University}}, funding-text = {{We would like to thank the Graduate Study Councils of the Iran University of Science and Technology and Shahid Beheshti University for financial support.}}, interhash = {52a65a23a767816146b1cdffbcd20759}, intrahash = {14fa7227c25d7fe9da003fe5dc32b9bf}, issn = {{1566-7367}}, journal = {{CATALYSIS COMMUNICATIONS}}, journal-iso = {{Catal. Commun.}}, keywords = {Hydrogen Sulfoxidation; Tetraphenyl-2,3-dihydroxy-2,3-chlorin complex; metal peroxide} {Tetraphenylporpholactone}, keywords-plus = {{DIELS-ALDER REACTIONS; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; CHIRAL LIGANDS; SULFIDES; EFFICIENT; METALLOPORPHYRINS; PORPHYRINS; SULFONES; ALCOHOLS}}, language = {{English}}, month = {{DEC 15}}, number = {{4}}, number-of-cited-references = {{33}}, orcid-numbers = {{Azhdari Tehrani, Alireza/0000-0001-8070-9164}}, pages = {{232-235}}, publisher = {{ELSEVIER SCIENCE BV}}, research-areas = {{Chemistry}}, researcherid-numbers = {{Mir Mohammad Sadegh, Bahareh/H-3303-2011 Azhdari Tehrani, Alireza/B-8499-2014 }}, times-cited = {{17}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction}}, type = {{Article}}, unique-id = {{ISI:000272979900002}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{25}}, volume = {{11}}, web-of-science-categories = {{Chemistry, Physical}}, year = {{2009}} }