Abstract
The crustal Urey cycle of CO2 involving silicate weathering and metamorphism
acts as a dynamic climate buffer. In this cycle, warmer temperatures
speed silicate weathering and carbonate formation, reducing atmospheric
CO2 and thereby inducing global cooling. Over long periods of time,
cycling of CO2 into and out of the mantle also dynamically buffers
CO2. In the mantle cycle, CO2 is outgassed at ridge axes and island
arcs, while subduction of carbonatized oceanic basalt and pelagic
sediments returns CO2 to the mantle. Negative feedback is provided
because the amount of basalt carbonatization depends on CO2 in seawater
and therefore on CO2 in the air. On the early Earth, processes involving
tectonics were more vigorous than at present, and the dynamic mantle
buffer dominated over the crustal one. The mantle cycle would have
maintained atmospheric and oceanic CO2 reservoirs at levels where
the climate was cold in the Archean unless another greenhouse gas
was important. Reaction of CO2 with impact ejecta and its eventual
subduction produce even lower levels of atmospheric CO2 and small
crustal carbonate reservoirs in the Hadean. Despite its name, the
Hadean climate would have been freezing unless tempered by other
greenhouse gases.
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