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Coordinative Approach to Mediated Electron Transfer: Ruthenium Complexed to Native Glucose Oxidase

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Angewandte Chemie International Edition, 38 (6): 804--807 (марта 1999)

Аннотация

Catalytically and electrocatalytically very active and stable are the complexes Ru(LL)-GO, which are extremely readily accessible from glucose oxidase (GO) and the RuII complexes cis-Ru(LL)2Cl2 (LL=bpy, phen). These provide an unprecedentedly high amplification coefficient I/Io (see cyclic voltammograms) even at high scan rates and, correspondingly, very high rates of intramolecular electron transfer.

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